699-61-6

Basic information

• Product Name: Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone
• Synonyms: Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone
• CAS NO: 699-61-6
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.208
• Mol File: 699-61-6.mol
• Article Data: 6

Chemical Properties

• Melting Point: 26-27 °C
• Boiling Point: 260.5°C at 760 mmHg
• Flash Point: 102.7°C
• Appearance: /
• Density: 1.07g/cm³
• Vapor Pressure: 0.0122mmHg at 25°C
• Refractive Index: 1.488
• Storage Temp.: Sealed in dry,Store in freezer, under -20°C
• CAS DataBase Reference: Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone(699-61-6)
• EPA Substance Registry System: Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone(699-61-6)

Safety Data

• Hazardous Substances Data: 699-61-6(Hazardous Substances Data)

Usage

General Description

Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone is a chemical compound with a cyclic structure that contains a lactone group. It is also known as gamma-hydroxy-cyclohexanepropionic acid lactone. Cyclohexanepropanoicacid,1-hydroxy-,gamma-lactone is used in the flavor and fragrance industry as a flavoring agent due to its sweet, creamy, and coconut-like odor. It is commonly found in food products and can also be used in cosmetic and personal care products as a fragrance ingredient. This chemical compound is generally recognized as safe for use in food and is commonly added to a variety of products to enhance their aroma and taste.

InChI:InChI=1/C9H14O2/c10-8-4-7-9(11-8)5-2-1-3-6-9/h1-7H2

Upstream product

• 3395-91-3 Methyl 3-bromopropionate 
• 108-94-1 cyclohexanone 
• 107-13-1 acrylonitrile 
• 292638-85-8 acrylic acid methyl ester 
• 185-70-6 1-oxaspiro(2.5)octane 
• 105-36-2 ethyl bromoacetate 
• 1940-19-8 1-vinylcyclohexanol 
• 79-10-7 acrylic acid 
• 922-67-8 propynoic acid methyl ester 
• 183207-21-8 N,N-Dibenzyl-3-(1-hydroxy-cyclohexyl)-propionamide 

Downstream Products

• 65173-43-5 ethyl 3-(cyclohex-1-en-1-yl)propionate 
• 101861-89-6 3-(1-hydroxy-cyclohexyl)-propionic acid amide 
• 69245-96-1 4-(cyclohex-1-en-1-yl)butan-2-one/4-cyclohexylidenebutan-2-one 
• 927-49-1 dipentyl ketone 
• 60416-25-3 3-(cyclohex-1-enyl)propionaldehyde 
• 1394163-03-1 C₁₆H₂₅NO 
• 176-91-0 1-oxaspiro<4,5>decane 
• 6963-45-7 1-(3-hydroxypropyl)-cyclohexanol 
• 73089-99-3 1-[2-(1-Hydroxycyclopentyl)ethyl]cyclohexanol 

Relevant articles and documents

Samarium (II) iodide-induced intermolecular coupling of a,b-unsaturated esters with ketones: Reactions of methyl propiolate and ethyl buta-2,3-dienoate with cyclohexanone and its application to synthesis of a terpene carboxylic acid

The reactions of methyl propiolate and ethyl buta-2,3-dienoate with cyclohexanone induced by SmI2 occurred either at a- or b-position to yield different products depending on with or without a proton source. The synthesis of terpenic acid was demonstrated using this reaction.

Homoaldol and aldol reactions from common enolates and oxirance: Reaction of reductively generated chromium enolates through cationic rearrangement

Enolates generated from α-bromo esters by the reduction with Bu6CrLi3 react with oxiranes to afford γ-hydroxy esters and β-hydroxy esters, depending on the Lewis acid used as a promoter.

Samarium diiodide promoted spirolactonization of cycloalkanones

Reaction of cycloalkanones with methyl 3-bromopropionate and SmI2 afforded formation of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-1-oxaspiro[n,m]alkan-2-ones.