69901-42-4

Basic information

• Product Name: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate
• Synonyms: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate
• CAS NO: 69901-42-4
• Molecular Weight: 526.757
• Mol File: 69901-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate(69901-42-4)
• EPA Substance Registry System: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate(69901-42-4)

Safety Data

• Hazardous Substances Data: 69901-42-4(Hazardous Substances Data)

Upstream product

• 33919-05-0 2,4,6-tri-tert-butyl-4-hydroperoxycyclohexa-2,5-dienone 
• 40056-43-7 3,5-di-tert-butyl-4-hydroxybenzoyl chloride 

Downstream Products

• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 
• 2455-14-3 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone 
• 1421-49-4 3,5-Di-tert-butyl-4-hydroxybenzoic acid 
• 69217-39-6 2,4,6-tri-tert-butyl-4-tert-butoxy-2,5-cyclohexadienone 
• 732-26-3 2,4,6-tri-tert-butylphenoxol 
• 4971-61-3 2,4,6-tri-tert-butyl-4-hydroxy-2,5-cyclohexadienone 

Relevant articles and documents

Peroxy Esters. 9. Base- and Radical-Induced Decomposition of 1-Alkyl-3,5-di-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-Di-tert-butyl-4-hydroxyperbenzoates

The title peroxy esters 1, when deprotonated with t-BuOK in DMF to the corresponding phenolate anions, decompose even at -78 deg C to give compounds 2-10.These compounds result undoubtedly from homolysis of the peroxy bond in 1, indicating that the generation of a carbanion at the α-position of the acyl group in peroxy esters (via resonance in the present case) induces ready homolysis of the peroxy bond.The oxidation of 1 with one-electron oxidizing agents gives rise to the corresponding phenoxy radicals, which also induce homolysis of the peroxy bond.