70021-83-9

Basic information

• Product Name: 2-Naphthalenecarboxamide, N-phenyl-
• CAS NO: 70021-83-9
• Molecular Formula: C17H13NO
• Molecular Weight: 247.296
• Mol File: 70021-83-9.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: 2-Naphthalenecarboxamide, N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthalenecarboxamide, N-phenyl-(70021-83-9)
• EPA Substance Registry System: 2-Naphthalenecarboxamide, N-phenyl-(70021-83-9)

Safety Data

• Hazardous Substances Data: 70021-83-9(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 2243-83-6 2-naphthaloyl chloride 
• 93-09-4 naphthalene-2-carboxylate 
• 60-29-7 diethyl ether 
• 10026-13-8 phosphorus pentachloride 
• 872789-85-0 [2]naphthyl-phenyl ketone oxime 
• 5378-52-9 phenyl-1H-tetrazole 
• 66-99-9 β-naphthaldehyde 
• 622-16-2 1,3-Diphenylcarbodiimide 
• 4532-28-9 2,4,6-tris-naphthalen-2-yloxy-[1,3,5]triazine 
• 95-14-7 1,2,3-Benzotriazole 
• 3007-91-8 ethyl-2-naphthoate 
• 80192-95-6 N-methyl-N-phenyl-2-naphthylamide 
• 300402-59-9 N-(2-chlorophenyl)-2-naphthamide 

Downstream Products

• 62-53-3 aniline 
• 300402-71-5 N-(4-fluorophenyl)-2-naphthalenecarboxamide 
• 1256360-86-7 C₂₇H₂₁NO₃ 
• 68427-26-9 4-(naphthalen-2-yl)butan-2-one 
• 259817-03-3 methyl 2-diazo-3-[N-(2-naphthoyl)-N-phenylamino]-3-oxopropanoate 
• 5866-82-0 (Naphthalene-2-carbonyl)-phenyl-carbamic acid isopropyl ester 
• 83738-55-0 (4-(diethylamino)phenyl)(naphthalen-2-yl)methanone 
• 83738-57-2 (4-(dimethylamino)phenyl)(naphthalen-2-yl)methanone 
• 66-99-9 β-naphthaldehyde 
• 108979-85-7 5-(naphthalen-2-yl)-1-phenyl-1H-tetrazole 

Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of N-Acyl and N-Sulfonyl Benzotriazoles with Diverse Nitro Compounds: Rapid Access to Amides and Sulfonamides

Herein we report a Ni-catalyzed reductive transamidation of conveniently available N-acyl benzotriazoles with alkyl, alkenyl, and aryl nitro compounds, which afforded various amides with good yields and a broad substrate scope. The same catalytic reaction conditions were also applicable for N-sulfonyl benzotriazoles, which could undergo smooth reductive coupling with nitroarenes and nitroalkanes to afford the corresponding sulfonamides.

Chromium-catalyzed ligand-free amidation of esters with anilines

Amides are important structural motifs in pharmaceutical and agrochemical chemistry because of the intriguing biological active properties. We report here the amidation of commercially available esters with anilines that was promoted by low-cost and air-stable chromium(III) pre-catalyst combined with magnesium, providing access to amides. This reaction occurs without the use of external ligands in a simple operation. Mechanistic studies indicate that a reactive aminated Cr species responsible for the amidation can be considered, which may be formed by reaction of low-valent Cr with aniline followed by reduction with hydrogen evolution.

Exploration of Cu-catalyzed regioselective hydrodehalogenation of o-haloanilides using EtOH as hydrogen source

In present work, we have explored a Cu(acac)2/vasicine-catalyzed regioselective hydrodehalogenation methodology of o-haloanilides using EtOH as hydrogen source and solvent. The catalytic system could selectively dehalogenate 2-Br and 2-I, and features regioselective, efficient and functional group tolerance.