7022-98-2

Basic information

• Product Name: 1-Propanol, 2-chloro-, benzoate
• CAS NO: 7022-98-2
• Molecular Formula: C10H11ClO2
• Molecular Weight: 198.649
• Mol File: 7022-98-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-Propanol, 2-chloro-, benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanol, 2-chloro-, benzoate(7022-98-2)
• EPA Substance Registry System: 1-Propanol, 2-chloro-, benzoate(7022-98-2)

Safety Data

• Hazardous Substances Data: 7022-98-2(Hazardous Substances Data)

Usage

Molecular structure

A propanol molecule with a chlorine atom attached to the second carbon and a benzoate group attached to the first carbon.

Usage

Commonly used as a solvent in various industrial applications, including the production of dyes, perfumes, and pharmaceuticals. Also used as an intermediate in the synthesis of other organic compounds.

Safety precautions

Potential health risks, should be handled with care and used in a well-ventilated area with suitable protective equipment.

Upstream product

• 98-88-4 benzoyl chloride 
• 75-56-9 methyloxirane 
• 2568-25-4 4-methyl-2-phenyl-1,3-dioxolane 

Relevant articles and documents

Hydrogenation of alkenes via cooperative hydrogen atom transfer

Radical hydrogenation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane isomers. Current single-catalyst methods require stoichiometric oxidant in addition to hydride (H-) source to function. Here we report a new approach to radical hydrogenation: cooperative hydrogen atom transfer (cHAT), where each hydrogen atom donated to the alkene arrives from a different catalyst. Further, these hydrogen atom (H?) equivalents are generated from complementary hydrogen atom precursors, with each alkane requiring one hydride (H-) and one proton (H+) equivalent and no added oxidants. Preliminary mechanistic study supports this reaction manifold and shows the intersection of metal-catalyzed HAT and thiol radical trapping HAT catalytic cycles to be essential for effective catalysis. Together, this unique catalyst system allows us to reduce a variety of unactivated alkene substrates to their respective alkanes in high yields and diastereoselectivities and introduces a new approach to radical hydrogenation.

A new synthetic method for haloalkyl carboxylic esters from the radical ring cleavage of cyclic acetals with haloform

A one-pot reaction of cyclic acetals with haloform catalyzed by AIBN(2,2'-azobisisobutyronitrile) provides a novel convenient way to prepare directly haloalkyl carboxylic esters in good yields.

REGIOSELECTIVE RING CLEAVAGE OF OXIRANES CATALYZED BY ORGANOTIN HALIDE - TRIPHENYLPHOSPHINE COMPLEX

Vicinal chloroesters are formed in high yield from the reaction of oxiranes and benzoyl chloride in the presence of organotin halide - triphenylphosphine complex with enhanced regioselectivity in oxirane ring cleavage.