70972-96-2

Basic information

• Product Name: N-Chloro-N-methyl-m-nitrobenzylamin
• CAS NO: 70972-96-2
• Molecular Weight: 200.625
• Mol File: 70972-96-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Chloro-N-methyl-m-nitrobenzylamin(CAS DataBase Reference)
• NIST Chemistry Reference: N-Chloro-N-methyl-m-nitrobenzylamin(70972-96-2)
• EPA Substance Registry System: N-Chloro-N-methyl-m-nitrobenzylamin(70972-96-2)

Safety Data

• Hazardous Substances Data: 70972-96-2(Hazardous Substances Data)

Upstream product

• 19499-61-7 methyl-(3-nitro-benzyl)-amine 

Downstream Products

• 121004-44-2 N-methyl-1-(3-nitrophenyl)methanimine 

Relevant articles and documents

Reactions of N-Halogenobenzylmethylamines with Triethylamine in Acetonitrile. Effect of Leaving Group upon the Imine-forming Transition State

Reactions of N-halogenobenzylmethylamines (1) and (2) with Et3N-MeCN have been investigated kinetically.Eliminations from (1) and (2) were quantitative and regiospecific, producing only benzylidenemethylamines.For the elimination reaction of (1) with Et3N, kH/kD 5.7, ρ 0.88, 9.1 kcal mol-1, and -42.4 cal mol-1 K-1 were determined.The transition-state structure is assessed as being highly symmetric with similar extents of Cβ-H and Nα-Cl bond cleavage, little carbanionic character, and significant ?-bond formation.The structure of the transition state changes only slightly with the change in the leaving group from Cl to Br.