72443-64-2

Basic information

• Product Name: BenzeneMethanaMine, 3-broMo-N,N,2-triMethyl-
• Synonyms: BenzeneMethanaMine, 3-broMo-N,N,2-triMethyl-;[(3-broMo-2-Methylphenyl)Methyl]diMethylaMine
• CAS NO: 72443-64-2
• Molecular Formula: C10H14BrN
• Molecular Weight: 228.12886
• Mol File: 72443-64-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BenzeneMethanaMine, 3-broMo-N,N,2-triMethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: BenzeneMethanaMine, 3-broMo-N,N,2-triMethyl-(72443-64-2)
• EPA Substance Registry System: BenzeneMethanaMine, 3-broMo-N,N,2-triMethyl-(72443-64-2)

Safety Data

• Hazardous Substances Data: 72443-64-2(Hazardous Substances Data)

Upstream product

• 43180-39-8 dimethyl<(phenylthio)methyl>amine 
• 69321-60-4 2,6-dibromotoluene 

Downstream Products

• 72443-63-1 Dimethyl<2-methyl-3-<(dimethylamino)methyl>phenyl>silanol 

Relevant articles and documents

Ylide Reactions of Benzyldimethylammonium Halides

Deprotonation of benzyldimethylammonium halides (10) with sodium amide or n-butyllithium afforded silylated ylide intermediates 11, which were rearranged into N,N-dimethyl-2-benzylamines (13) accompanied by the formation of Sommelet-Hauser and Stevens rearrangement products (12 and 22).The ylide formation by the cleavage of carbon-silicon bonds also is discussed in the reaction of 10 with sodium amide and lithium aluminum hydride.