7251-30-1Relevant articles and documents
Syntheses of the Terpenoid Precursors Cyclopent-2-enone and Cyclohex-2-enone Diesters
Kadas, I.,Morvai, V.,Arvai, G.,Toeke, L.,Szoelloesy, A.,et al.
, p. 107 - 118 (2007/10/02)
Two reaction pathways were elaborated for the practical and convenient syntheses of the title compounds.The first route applies a bromination-dehydrobromination sequence to introduce the double bond into 1-alkoxycarbonyl-2-oxocycloalkylacetic and propioni
CATALYST DEPENDENT MECHANISTIC PATHS IN THE REACTIONS OF ETHYL DIAZOACETATE WITH β-KETO ESTERS
Lottes, Andrew C.,Landgrebe, John A.,Larsen, Kristin
, p. 4093 - 4096 (2007/10/02)
The catalyzed decomposition of ethyl diazoacetate in the presence of β-keto esters produces regioisomeric enol ethers and the diester from formal carbenoid insertion into the α-C-H bond.The product distribution is very catalyst dependent.