72596-34-0Relevant articles and documents
Manganese(III)-mediated direct phosphonylation of arenes
Xu, Wei,Zou, Jian-Ping,Zhang, Wei
experimental part, p. 2639 - 2643 (2010/06/16)
Manganese (III)-promoted direct phosphonylation of mono- and disubstituted arenes with dialkylphosphite afforded regioselective dialkylphosphonates in good yields. The reactions can apply to arenes bearing electron-donating groups and electron-withdrawing
Oxidative Phoshonylation of Aromatics with Ammonium Cerium(IV) Nitrate
Kottmann, Hariolf,Skarzewski, Jacek,Effenberger, Franz
, p. 797 - 801 (2007/10/02)
Arylphosphonates 5 and 6 can be prepared in good yields in a one-step synthesis starting from arenes with tri- or diethylphosphites and cerium ammonium nitrate (CAN) as oxidant.The seletivity of the oxidative phosphonylation is relatively low; the reactive species is a phosphite radical cation.