7302-06-9

Basic information

• Product Name: Benzene, 1,1'-(2-methyl-1-propene-1,3-diyl)bis-, (E)-
• CAS NO: 7302-06-9
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 7302-06-9.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(2-methyl-1-propene-1,3-diyl)bis-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(2-methyl-1-propene-1,3-diyl)bis-, (E)-(7302-06-9)
• EPA Substance Registry System: Benzene, 1,1'-(2-methyl-1-propene-1,3-diyl)bis-, (E)-(7302-06-9)

Safety Data

• Hazardous Substances Data: 7302-06-9(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 102-04-5 1,3-Diphenylpropanone 
• 673-32-5 1-Phenylprop-1-yne 
• 620-05-3 iodomethylbenzene 
• 591-51-5 phenyllithium 
• 42117-23-7 2-methyl-1,3-diphenylpropan-2-ol 
• 1504-55-8 (E)-3-phenyl-2-methyl-2-propenol 
• 98-80-6 phenylboronic acid 
• 849943-87-9 (Z)-1,3-diphenylprop-1-en-2-yl 4-methylbenzenesulfonate 
• 13061-96-6 dihydroxy-methyl-borane 
• 6921-34-2 benzylmagnesium chloride 
• 252975-30-7 selenophosphoric acid Se-(1-benzoyl-1-methyl-2-oxo-2-phenylethyl) ester O,O-diethyl ester 
• 14213-54-8 2-Benzyl-3-phenylpropyldimethylammonium-iodid 
• 637-50-3 1-phenylpropene 

Downstream Products

• 1370037-96-9 (E)-butyl 3-(2-((E)-2-methyl-3-phenylallyl)phenyl)acrylate 
• 2883-08-1 1,3-dicyclohexyl-2-methyl-propane 
• 57338-06-4 1,2-epoxy-2-methyl-1,3-diphenyl-propane 
• 94897-34-4 3,4-diphenyl-2-butanone 

Relevant articles and documents

Nickel-Catalyzed Arylation of C(sp3)-O Bonds in Allylic Alkyl Ethers with Organoboron Compounds

A nickel-catalyzed cross-coupling of allylic alkyl ethers with organoboron compounds through the cleavage of the inert C(sp3)-O(alkyl) bonds is described. Several types of allylic alkyl ethers can be coupled with various boronic acids or their derivatives to give the corresponding products in good to excellent yields with wide functional group tolerance and excellent regioselectivity. The gram-scale reaction and late-stage modification of biologically active compounds further prove the practicality of this synthetic method.

Iron-Catalyzed Remote Arylation of Aliphatic C-H Bond via 1,5-Hydrogen Shift

Catalytic amounts of an iron(III) salt and a N-heterocyclic carbene ligand catalyze the arylation of 2-iodoalkylarenes with diphenylzinc selectively at the C-H bond of the alkyl side chain. Several lines of evidence suggest that the iron catalyst reacts with the aryl iodide moiety of the substrate to generate an aryliron intermediate that behaves in a radical manner and cleaves the aliphatic C-H bond through 1,5-hydrogen transfer; the resulting alkyliron intermediate undergoes reductive elimination to give the arylated product.

Chemo- and regioselective reductive deoxygenation of 1-en-4-yn-ols into 1,4-enynes through FeF3 and TfOH co-catalysis

We report chemo- and regioselective direct reductive deoxygenation of 1-en-4-yn-3-ols into 1,4-enynes through FeF3 and TfOH cooperative catalysis under NBSH-mediated conditions. Further, we show the efficient synthesis of a pharmaceutically significant 1,4-enyne. The present methodology can also be used for chemo- and regioselective direct deoxygenation of other alcohols.