73564-69-9Relevant articles and documents
Solvent Influence on the Magnetic Properties of Iron(II) Spin-Crossover Coordination Compounds with 4,4′-Dipyridylethyne as Linker
Dankhoff, Katja,Lochenie, Charles,Puchtler, Florian,Weber, Birgit
, p. 2136 - 2143 (2016)
New iron(II) coordination polymers with solvent-dependent spin-crossover behaviour have been synthesised by using an N2O2 Schiff base like ligand and 4,4′-dipyridylethyne as the bridging axial ligand in different solvents. The effects of different solvents and preparation methods (temperature, concentration) on the magnetic properties have been investigated. Annealing the coordination polymers prepared by the same method but in different solvents led to the same compound exhibiting the same three-step spin crossover independent of the magnetic properties of the solvated species. The X-ray structures of the axial ligand, an iron(II) dimer and one of the iron(II) coordination polymers are discussed. Powder X-ray diffraction analysis was additionally used for further comparison of the compounds.
Electrochemical investigation of structurally varied azinium scaffolds
Bure?, Filip,Bure?ová, Zuzana,Klikar, Milan,Kví?ala, Jaroslav,Mazúr, Petr,Mike?ová, Michaela,Rak, Kamil
, p. 8830 - 8839 (2021/10/22)
Inspired by the successful utilization of aziniums as anolytes in redox-flow batteries, we have designed and prepared a systematically extended series of (di)azinium compounds based on pyrazine, bipyridine, 1,5-naphthyridine, 3,8-phenanthroline, (E)-4,4′-
The Covalent and Coordination Co-Driven Assembly of Supramolecular Octahedral Cages with Controllable Degree of Distortion
Bao, Shu-Jin,Xu, Ze-Ming,Ju, Yun,Song, Ying-Lin,Wang, Heng,Niu, Zheng,Li, Xiaopeng,Braunstein, Pierre,Lang, Jian-Ping
supporting information, p. 13356 - 13361 (2020/09/03)
Discovering and constructing novel and fancy structures is the goal of many supramolecular chemists. In this work, we propose an assembly strategy based on the synergistic effect of coordination and covalent interactions to construct a set of octahedral s