73643-89-7Relevant articles and documents
Transition metal chemistry of phosphorus based ligands: Synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH 2(Me)NPPh2}]
Balakrishna, Maravanji S.,Walawalker, Mrinalini G.
, p. 76 - 80 (2007/10/03)
The bis(phosphine), Ph2PN(CH3)CH2CH2N(CH 3)PPh2 reacts with Group 6 metal carbonyl derivatives, [ReBr(CO)3(NCMe)2] and [MCl2(COD)] (M=Pd or Pt) to give the corresponding seven-membered chelate complexes. The compounds have been characterized by elemental analysis, IR and NMR spectroscopic data. The structure of the rhenium complex, [ReBr(CO)3{Ph2PN(CH3)CH2CH 2(CH3)NPPh2}] has been confirmed by X-ray crystallography.