73654-59-8

Basic information

• Product Name: 1,2,4-tri-O-acetyl-3-O-benzyl-α,β-D-xylopyranose
• CAS NO: 73654-59-8
• Molecular Weight: 366.368
• Mol File: 73654-59-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2,4-tri-O-acetyl-3-O-benzyl-α,β-D-xylopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4-tri-O-acetyl-3-O-benzyl-α,β-D-xylopyranose(73654-59-8)
• EPA Substance Registry System: 1,2,4-tri-O-acetyl-3-O-benzyl-α,β-D-xylopyranose(73654-59-8)

Safety Data

• Hazardous Substances Data: 73654-59-8(Hazardous Substances Data)

Upstream product

• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 80235-68-3 3-O-benzyl-D-xylopyranose 
• 108-24-7 acetic anhydride 

Downstream Products

• 1346691-03-9 C₁₆H₂₀O₆ 
• 1346691-04-0 C₁₂H₁₆O₄ 
• 1346691-05-1 C₄₈H₆₈O₃₀ 
• 1269466-61-6 4-methylphenyl 2-O-benzoyl-3-O-benzyl-1-thio-β-D-xylopyranoside 
• 1269466-50-3 p-methylphenyl 3-O-benzyl-1-thio-β-D-xylopyranoside 
• 1432612-85-5 N,3-O-dibenzyl-2,4-dideoxy-2,4-imino-L-ribonic acid 
• 1432612-84-4 methyl N,3-O-dibenzyl-2,4-dideoxy-2,4-imino-L-ribonate 
• 1432612-82-2 methyl N,3-O-dibenzyl-2,4-dideoxy-2,4-imino-β-L-ribopyranoside 
• 1432612-80-0 methyl N,3-O-dibenzyl-2,4-dideoxy-2,4-imino-β-L-ribopyranoside 
• 1432612-79-7 methyl 3-O-benzyl-2,4-di-O-trifluoromethanesulfonyl-β-D-xylopyranoside 
• 1432612-81-1 C₁₉H₂₁NO₃ 
• 72521-39-2 methyl 3-O-benzyl-β-D-xylopyranoside 
• 1432612-86-6 methyl N,3-O-dibenzyl-2,4-dideoxy-2,4-imino-L-ribonamide 
• 74334-74-0 methyl 2,4-O-diacetyl-3-O-benzyl-β-D-xylopyranoside 

Relevant articles and documents

Automated synthesis of arabinoxylan-oligosaccharides enables characterization of antibodies that recognize plant cell wall glycans

Monoclonal antibodies that recognize plant cell wall glycans are used for high-resolution imaging, providing important information about the structure and function of cell wall polysaccharides. To characterize the binding epitopes of these powerful molecular probes a library of eleven plant arabinoxylan oligosaccharides was produced by automated solid-phase synthesis. Modular assembly of oligoarabinoxylans from few building blocks was enabled by adding (2-naphthyl)methyl (Nap) to the toolbox of orthogonal protecting groups for solid-phase synthesis. Conjugation-ready oligosaccharides were obtained and the binding specificities of xylan-directed antibodies were determined on microarrays. Automated synthesis meets plant research: Automated synthesis of plant oligosaccharides provides molecular tools for the characterization of important biological probes in plant research. The binding specificities of a collection of xylan-directed monoclonal antibodies have been determined by means of carbohydrate microarrays equipped with synthetic arabinoxylan fragments (see figure).

STUDIES DIRECTED TOWARD THE TOTAL SYNTHESIS OF POLYCAVERNOSIDE A. ENANTIOSELECTIVE SYNTHESIS OF THE DISACCHARIDE COMPONENT

Adaptation of the Mukaiyama-Nicolaou protocol to the coupling of a monounprotected thioglycoside to a glycosyl fluoride is capable of delivering the unusual disaccharide present in the title toxin.