73809-45-7

Basic information

• Product Name: 5,6-cis-1α-Hydroxyvitamin D₂ 3-acetate
• Synonyms: 5,6-cis-1α-Hydroxyvitamin D₂ 3-acetate
• CAS NO: 73809-45-7
• Molecular Weight: 454.693
• Mol File: 73809-45-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,6-cis-1α-Hydroxyvitamin D₂ 3-acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-cis-1α-Hydroxyvitamin D₂ 3-acetate(73809-45-7)
• EPA Substance Registry System: 5,6-cis-1α-Hydroxyvitamin D₂ 3-acetate(73809-45-7)

Safety Data

• Hazardous Substances Data: 73809-45-7(Hazardous Substances Data)

Upstream product

• 50-14-6 Vitamin D₂ 
• 72204-99-0 Vitamin D₂ tosylate 
• 74035-72-6 3,5-Cyclovitamin D₂ 
• 67657-85-6 1α-Hydroxy-3,5-cyclovitamin D₂ 
• 64-19-7 acetic acid 

Downstream Products

• 54573-75-0 1α-Hydroxyvitamin D₂ 

Relevant articles and documents

Direct C(1) Hydroxylation of Vitamin D3 and Related Compounds

A direct synthesis of C(1) hydroxylated vitamin D analogues from the corresponding vitamin D precursors has been developed.Allylic oxidation of 3,5-cyclovitamin D derivatives, readily obtained from the buffered solvolysis of vitamin D tosylates, with selenium dioxide yields 1α-hydroxylated 3,5-cyclovitamin D compounds which are smoothly converted to the desired 1α-hydroxyvitamin D derivatives by acid-catalyzed cycloreversion.Application of this scheme to vitamin D3 (1a), 25-hydroxyvitamin D3 (1b), and vitamin D2 (1c) affords the 1α-hydroxy products in ca.20 percent overall yield.