741259-14-3Relevant articles and documents
Synthesis and Properties of BODIPY Appended Tetraphenylethylene Scaffolds as Photoactive Arrays
Sample, Harry C.,Emandi, Ganapathi,Twamley, Brendan,Grover, Nitika,Khurana, Bhavya,Sol, Vincent,Senge, Mathias O.
, p. 4136 - 4143 (2021/08/24)
Tetraphenylethylene (TPE) and its derivatives exhibit excellent aggregation-induced emission (AIE) properties. The TPE unit is easily accessible, and many functional groups can be introduced in a facile manner to yield effective luminescent materials in both solution and the solid-state. It is because of this, several TPE-based compounds have been developed and applied in many areas, such as OLEDs and chemical sensors. Boron dipyrromethenes (BODIPYs) are a class of pyrrolic fluorophore of great interest with myriad application in both material science and biomedical applications. Through the combination of Pd-catalyzed cross-coupling reactions and traditional dipyrromethene chemistry, we present the syntheses of novel tetra-BODIPY-appended TPE derivatives with different distances between the TPE and BODIPY cores. The TPE-BODIPY arrays 6 and 9 show vastly differing AIE properties in THF/H2O systems, with 9 exhibiting dual-AIE, along with both conjugates being found to produce singlet oxygen (1O2). We presume the synthesized BODIPY-appended TPE scaffolds to be utilized for potential applications in the fields of light-emitting systems and theranostics.
Water-soluble Glucosamine-coated AIE-Active Fluorescent Organic Nanoparticles: Design, Synthesis and Assembly for Specific Detection of Heparin Based on Carbohydrate–Carbohydrate Interactions
Ji, Yan-ming,Liu, Guang-jian,Li, Cui-yun,Liu, Yi-chen,Hou, Min,Xing, Guo-wen
supporting information, p. 3295 - 3300 (2019/11/05)
Two water-soluble carbohydrate-coated AIE-activate fluorescent organic nanoparticles TPE3G and TPE4G were designed and synthesized for the detection of heparin. Different from the reported strategy, we not only utilized the general detection mechanism of
Functionalized metal-organic framework compounds, complexes formed therefrom, and methods of preparation and use thereof
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, (2019/10/01)
The invention discloses a functionalized metal-organic framework compounds, complexes formed therefrom, and methods of preparation and use thereof, wherein the molecular formula of the functionalizedmetal-organic framework compound is C36H22N7O4Zn, and th