74378-77-1

Basic information

• Product Name: 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane
• Synonyms: 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane
• CAS NO: 74378-77-1
• Molecular Weight: 268.249
• Mol File: 74378-77-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane(74378-77-1)
• EPA Substance Registry System: 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane(74378-77-1)

Safety Data

• Hazardous Substances Data: 74378-77-1(Hazardous Substances Data)

Upstream product

• 4187-59-1 trans-2-hydroxymethylcyclohexanol 
• 770-12-7 O-phenyl phosphorodichloridate 
• 74410-66-5 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane 
• 74410-72-3 2-chloro-2-oxo-5,6-tetramethylene-1,3,2-dioxaphosphorinane 
• 108-95-2 phenol 
• 78339-65-8 2-fluoro-2-oxo-5,6-tetrametylene-1,3,2-dioxaphosphorinane 
• 110-83-8 cyclohexene 

Downstream Products

• 3229-70-7 phenolate 
• 74410-66-5 2-phenoxy-2-oxo-trans-5,6-tetramethylene-1,3,2-dioxaphosphorinane 
• 73581-88-1 (4aS,8aR)-2-Oxo-hexahydro-2λ⁵-benzo[1,3,2]dioxaphosphinin-2-ol 
• 33073-66-4 dihydrogen trans-2-hydroxycyclohexylmethyl phosphate 

Relevant articles and documents

Silicon Phosphorus Analogies. Fluoride Activation of Nucleophilic Displacement at the Tetrahedral Phosphorus: An Example of Nucleophilic Assistance to Nucleophilic Substitution. 3

We report a mechanistic study of the activation of alcoholysis of the P-X bond (X= Cl, F) by F(1-).Cis and trans isomers of 2-halogeno-5-(chloromethyl)-5-methyl-2-oxo-1,3,2-dioxaphosphorinanes, 1 and 2, or their 2-thio analogues, 3 and 4, and epimeric 2-h