75073-97-1

Basic information

• Product Name: dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate
• Synonyms: dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate
• CAS NO: 75073-97-1
• Molecular Weight: 264.278
• Mol File: 75073-97-1.mol
• Article Data: 38

Chemical Properties

• CAS DataBase Reference: dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate(75073-97-1)
• EPA Substance Registry System: dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate(75073-97-1)

Safety Data

• Hazardous Substances Data: 75073-97-1(Hazardous Substances Data)

Upstream product

• 7443-25-6 dimethyl 2-(4-methoxybenzylidene)malonate 
• 1774-47-6 trimethylsulfoxonium iodide 
• 637-69-4 4-Methoxystyrene 
• 868-26-8 dimethyl 2-bromomalonate 
• 123-11-5 4-methoxy-benzaldehyde 
• 108-59-8 malonic acid dimethyl ester 
• 600-00-0 ethyl 2-bromoisobutyrate 
• 685-87-0 Diethyl 2-bromomalonate 
• 1379474-24-4 dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate 
• 145838-86-4 bis(methoxycarbonyl)(phenyliodinio)methanide 
• 75073-93-7 4-(4-Methoxy-phenyl)-4,5-dihydro-pyrazole-3,3-dicarboxylic acid dimethyl ester 
• 6773-29-1 dimethyl diazomalonate 

Downstream Products

• 1192554-09-8 C₁₇H₂₀O₆ 
• 1263081-99-7 dimethyl (E)-2-(4-methoxystyryl)malonate 
• 1181823-70-0 C₂₄H₂₇NO₅ 
• 1315455-98-1 C₂₁H₂₁NO₅ 
• 1402823-97-5 dimethyl 2-imino-5-(4-methoxyphenyl)pyrrolidine-3,3-dicarboxylate 
• 1462945-72-7 dimethyl 2-(2-((4-chlorophenyl)thio)-2-(4-methoxyphenyl)ethyl)malonate 
• 1629211-24-0 dimethyl 5-(4-methoxyphenyl)-2-phenylisoxazolidine-3,3-dicarboxylate 

Relevant articles and documents

An efficient generation of a functionalized tertiary-alkyl radical for copper-catalyzed tertiary-alkylative Mizoroki-Heck type reaction

α-Halocarbonyl compounds undergo β-hydrogen elimination to give conjugated olefins in the presence of a transition-metal catalyst. However, a copper/triamine catalyst system can induce the alkylative Mizoroki-Heck reaction of styrenes with tertiary-alkyl halides possessing a withdrawing group under very mild conditions. This reaction provides an efficient synthetic methodology for tertiary-alkylated styrenes.

(3+2)-Cycloaddition of Donor-Acceptor Cyclopropanes with Thiocyanate: A Facile and Efficient Synthesis of 2-Amino-4,5-dihydrothiophenes

An easy and efficient route to obtain 2-amino-4,5-dihydrothiophenes is presented. A formal (3+2)-cycloaddition of donor-acceptor cyclopropanes and ammonium thiocyanate catalyzed by Yb(OTf) 3delivers the desired products in good to excellent yields. A broad range of functional groups is tolerated during this process.

Electricity Driven 1,3-Oxohydroxylation of Donor-Acceptor Cyclopropanes: a Mild and Straightforward Access to β-Hydroxy Ketones

An unprecedented external oxidant-free electrochemical protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropane is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp3?Csp3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of molecular oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed.