75214-03-8Relevant articles and documents
Boron-Catalyzed Azide Insertion of α-Aryl α-Diazoesters
San, Htet Htet,Wang, Chun-Ying,Zeng, Hai-Peng,Fu, Shi-Tao,Tang, Xiang-Ying,Jiang, Min
, p. 4478 - 4485 (2019/05/01)
A challenging metal-free azide insertion of α-aryl α-diazoesters in the presence of B(C6F5)3 (5 mol %) was developed for the first time. The reaction features an easy operation, wide substrate scope, and mild conditions an
Synthesis ofα-azido ketones and esters using recyclable hypervalent iodine reagent
Telvekar, Vikas N.,Patile, Hemlata V.
experimental part, p. 131 - 135 (2011/02/27)
A simple and mild method for the preparation of αazido ketones and esters using hypervalent iodine reagent, 4,4'-bis-(dichloroiodo)-biphenyl, and sodium azide in 1,4-dioxane is discussed. Advantages of this system are easy workup, recyclable reagent, and
Intermolecular C-H and Si-H insertion reactions with halodiazoacetates
Bonge, Hanne Therese,Hansen, Tore
experimental part, p. 91 - 96 (2009/06/24)
Ethyl halodiazoacetates react with a range of substrates in regioselective rhodium(II)-catalysed C-H and Si-H insertion reactions giving α-halocarbonyl products in up to 82% yield. The halodiazoacetates are a novel class of diazo compounds that can undergo intermolecular carbenoid C-H insertion reactions, thus broadening the synthetic utility of such reactions. Georg Thieme Verlag Stuttgart.