75279-86-6Relevant articles and documents
New trisubstituted cyanopyrazoles and cyanoscorpionates
Kadel, Lava R.,Kromer, John R.,Moore, Curtis E.,Eichhorn, David M.
, p. 206 - 218 (2017/03/08)
New syntheses are reported to give pyrazoles with cyano substituents at the 4-position of the pyrazole ring and ethyl or isopropyl substituents at the 3-position, as well as pyrazoles with cyano substituents at the 4-position and alkyl/aryl/bromo substituents at both the 3- and 5-positions. Synthesis of scorpionates using tetradecane as a high-boiling solvent has been shown to be more efficient than the melt method and has led to new scorpionates using the newly synthesized pyrazoles. An unexpected complex is isolated in which the Ni(cyclam)2+moiety crystallizes with two cyanoscorpionates as counterions, without binding of the scorpionate ligands to the Ni atom.
Acylated cyanatoarenes - Reagents for convenient cyanations
Buttke,Niclas
, p. 681 - 683 (2007/10/03)
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Zirconium Complexes with the Trifunctional 3-Cyanopentane-2,4-dionate Ligand
Lock, George A.,Thompson, David W.
, p. 1265 - 1268 (2007/10/02)
Five zirconium complexes containing the 3-cyanopentane-2,4-dionate and 2-cyano-1-phenylbutane-1,3-dionate ligands (L) have been prepared: , , , and .Infrared data shows that all β-diketonate ligands are co-ordinated to the metal centre through both oxygens; however, in complexes of the type and the cyano-group appears to be co-ordinated as well.
