75467-59-3Relevant articles and documents
Silver ion-mediated coupling of 4-bromo-2,6-di-tert-butylcycohexa-2,5- dienone with phenols
Omura, Kanji
, p. 10031 - 10034 (2007/10/03)
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Oxidation of 2,6-Dimethoxyphenol with 2,6-Di-tert-butyl-4-propionylphenoxy Radical. Evidence for the Formation of an Intermediate "Radical Pair"
Brunow, Goesta
, p. 125 - 128 (2007/10/02)
In the title reaction an intermediate is formed which is stable at temperatures below -10 deg C.It gives no EPR signal.Warming leads to the formation of coerulignone and poly-2,6-dimethoxyphenylene oxide.Acid hydrolysis at low temperatures leads to cross-coupled products.The results are discussed in terms of a two-stage reaction mechanism for the formation of a bond between two phenoxy radicals.