75539-65-0Relevant articles and documents
Insect pheromones and their analogs LIX. A new method for the synthesis of components of the sex pheromones of insects of the genus Malacosoma
Kukovinets,Kasradze,Salimova,Odinokov,Galin,Fedorov
, p. 358 - 360 (2007/10/03)
A new method has been developed for the synthesis of the main components of the sex pheromones of insects of the Malacasoma genus that is based on the selective transformation of the product of the partial ozonolysis of cyclohexa-1,4-diene - methyl 6-oxohex-4E-enoate.
Highly stereoselective synthesis of Z,E conjugated diene type sex pheromones
Huang,Shi,Yang,Cai
, p. 3558 - 3560 (2007/10/02)
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Mass Spectra of Dodecadienic Compounds with a Conjugated Double Bond, Lepidopterous Sex Pheromones
Ando, Tetsu,Katagiri, Yoshio,Uchiyama, Masaaki
, p. 413 - 422 (2007/10/02)
All geometrical isomers of 5,7-, 6,8-, 7,9-, 8,10- and 9,11-dodecadien-1-ols, and their acetates and aldehyde derivatives were analyzed by electron impact mass spectrometry.The abundance of molecular ion (M(1+)) was observed in every spectrum, and the relative intensity of M(1+) tended to be strong if the compound possessed an (E)-double bond(s).In addition to M(1+), (1+) (alcohols) and (1+) (acetates), every dienic compound showed typical series of CnH(2n-2)(1+)CnH(2n-5)(1+) with abundance maxima around C4, C5, C6 or C7.Each double bond positional isomer characteristically yielded different ion peaks in the series, which were useful for its distinction from other isomers.These results indicate that the chemical structure of a natural pheromone of Lepidoptera is easily deduced successfully by GC-MS analysis if it is a conjugated dienic pheromone.