756491-45-9

Basic information

• Product Name: 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-3,3'-bis(4-methoxyphenyl)-, (1R)-
• CAS NO: 756491-45-9
• Molecular Formula: C38H34O6
• Molecular Weight: 586.684
• Mol File: 756491-45-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-3,3'-bis(4-methoxyphenyl)-, (1R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-3,3'-bis(4-methoxyphenyl)-, (1R)-(756491-45-9)
• EPA Substance Registry System: 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-3,3'-bis(4-methoxyphenyl)-, (1R)-(756491-45-9)

Safety Data

• Hazardous Substances Data: 756491-45-9(Hazardous Substances Data)

Upstream product

• 5720-07-0 4-methoxyphenylboronic acid 
• 142010-87-5 (±)?3,3'?dibromo?2,2'?bis(methoxymethyl)?1,1'?binaphthalene 
• 602-09-5 1,1'-bi-2-naphthol 
• 173831-50-0 rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene 

Downstream Products

• 1199631-29-2 (+/-)-3,3'-bis(4-methoxyphenyl)-2,2'-dihydroxy-1,1'-binaphthyl 

Relevant articles and documents

Photocatalyzed E→Z Contra-thermodynamic Isomerization of Vinyl Boronates with Binaphthol

The photocatalytic contra-thermodynamic E→Z isomerization of vinyl boronates by using a binaphthol catalyst is disclosed. The reaction, based on the transient formation of a suitable chromophore with a BINOL derivative as the catalyst, allowed geometrical isomerization in good-to-excellent Z/E ratio and excellent-to-quantitative yields. The mechanism of this E→Z contra-thermodynamic isomerization was studied, and the formation of a transient chromophore species is suggested.