77004-05-8

Basic information

• Product Name: 3-methyl-1-(phenylthio)-3-buten-2-one
• Synonyms: 3-methyl-1-(phenylthio)-3-buten-2-one
• CAS NO: 77004-05-8
• Molecular Weight: 192.282
• Mol File: 77004-05-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-methyl-1-(phenylthio)-3-buten-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-1-(phenylthio)-3-buten-2-one(77004-05-8)
• EPA Substance Registry System: 3-methyl-1-(phenylthio)-3-buten-2-one(77004-05-8)

Safety Data

• Hazardous Substances Data: 77004-05-8(Hazardous Substances Data)

Upstream product

• 13307-75-0 (phenylthio)methyllithium 
• 85660-63-5 1-diazo-3-methyl-3-phenylthio-2-butanone 
• 62034-61-1 2-methyl-2-(phenylthio)propanoyl chloride 
• 85660-54-4 3-chloro-3-methyl-1-phenylthio-2-butanone 
• 77003-92-0 2-methoxy-3-methyl-1-phenylthio-1,3-butadiene 
• 81306-15-2 3-methyl-1-phenylthio-3-buten-2-ol 

Downstream Products

• 81389-47-1 (1S,3S,4R)-7-Hydroxy-1-methyl-3-phenylsulfanyl-bicyclo[2.2.1]heptan-2-one 
• 81389-44-8 (1S,3S,4R)-7-Hydroxy-1,4-dimethyl-3-phenylsulfanyl-bicyclo[2.2.1]heptan-2-one 
• 81389-38-0 1-((1S,2R)-4-Methyl-2-phenylsulfanyl-3-trimethylsilanyloxy-cyclohex-3-enyl)-ethanone 
• 81389-37-9 (4aS,5S,7R,8aR)-7-Methyl-5-phenylsulfanyl-4a,7,8,8a-tetrahydro-5H-naphthalene-1,4,6-trione 
• 81389-36-8 (3aS,4S,7aR)-6-Methyl-4-phenylsulfanyl-5-trimethylsilanyloxy-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione 
• 81389-40-4 (2S,3R,6R)-3-Acetyl-6-methyl-2-phenylsulfanyl-cyclohexanone 
• 81389-39-1 (2S,3R,6S)-3-Acetyl-6-methyl-2-phenylsulfanyl-cyclohexanone 
• 81389-42-6 (1R,2S,4R)-4-Methyl-3-oxo-2-phenylsulfanyl-cyclohexanecarboxylic acid methyl ester 
• 81389-41-5 (1R,2S,4S)-4-Methyl-3-oxo-2-phenylsulfanyl-cyclohexanecarboxylic acid methyl ester 
• 81027-67-0 (3aS,4S,7aR)-6-Methyl-2-phenyl-4-phenylsulfanyl-5-trimethylsilanyloxy-3a,4,7,7a-tetrahydro-isoindole-1,3-dione 
• 81389-34-6 (Z)-3-methyl-1-(phenylthio)-2-<(trimethylsilyl)oxy>-1,3-butadiene 

Relevant articles and documents

NUCLEOPHILIC SUBSTITUTION OF α-HALO KETONES. XXI. STRUCTURE-REACTIVITY RELATIONSHIPS IN THE ACETOLYSIS OF 3-SUBSTITUTED 1-CHLORO-3-PHENYLTHIO-2-PROPANONES

The acetolyses of α-chloro ketones 1a-d have been re-investigated under standard conditions and compared with those of the corresponding isomeric substrates 2a-d.It has been shown that participation by the neighbouring phenylthio group, involving a 1-3 shift of the latter, does occur in part even in the case of 1d, while it is the only process in the case of 1e.A few structure-reactivity relationships in the two series of substrates are discussed.

RAPID, HIGH YIELD CLEAVAGE OF ENOL AND DIENOL METHYL ETHERS UNDER MILD CONDITIONS USING CHLOROTRIMETHYLSILANE/SODIUM IODIDE

A number of enol and dienol methyl ethers are rapidly cleaved to aldehydes and ketones in quantitative yields by the use of chlorotrimethylsilane/sodium iodide.