77381-79-4

Basic information

• Product Name: (1aR)-5ξ-hydroxy-1.1.7c.7ac-tetramethyl-(1arH.7bcH)-1a.2.3.5.6.7.7a.7b-octahydro-1H-cyclopropa[a]naphthalene
• CAS NO: 77381-79-4
• Molecular Weight: 220.355
• Mol File: 77381-79-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1aR)-5ξ-hydroxy-1.1.7c.7ac-tetramethyl-(1arH.7bcH)-1a.2.3.5.6.7.7a.7b-octahydro-1H-cyclopropa[a]naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: (1aR)-5ξ-hydroxy-1.1.7c.7ac-tetramethyl-(1arH.7bcH)-1a.2.3.5.6.7.7a.7b-octahydro-1H-cyclopropa[a]naphthalene(77381-79-4)
• EPA Substance Registry System: (1aR)-5ξ-hydroxy-1.1.7c.7ac-tetramethyl-(1arH.7bcH)-1a.2.3.5.6.7.7a.7b-octahydro-1H-cyclopropa[a]naphthalene(77381-79-4)

Safety Data

• Hazardous Substances Data: 77381-79-4(Hazardous Substances Data)

Upstream product

• 17334-55-3 β-gurjunene 

Downstream Products

• 28398-06-3 (1aR)-5-oxo-1.1.7c.7ac-tetramethyl-(1arH.7bcH)-1a.2.3.5.6.7.7a.7b-octahydro-1H-cyclopropa[a]naphthalene 

Relevant articles and documents

Synthetic Photochemistry. XXI. The Sensitized Photooxygenation of Calarene. A Facile Hock Cleavage of an Allylhydroperoxide and Structure Revision for Aristolenols

An allylic hydroperoxide formed by the sensitized photooxidation of calarene causes a Hock cleavage.A revised stereochemistry of an aristolenol is given on the basis of the direction of oxygenation.