77659-49-5

Basic information

• Product Name: Tricarbonyl(tetramethyldiphosphan)nickel
• Synonyms: Tricarbonyl(tetramethyldiphosphan)nickel
• CAS NO: 77659-49-5
• Molecular Weight: 264.808
• Mol File: 77659-49-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Tricarbonyl(tetramethyldiphosphan)nickel(CAS DataBase Reference)
• NIST Chemistry Reference: Tricarbonyl(tetramethyldiphosphan)nickel(77659-49-5)
• EPA Substance Registry System: Tricarbonyl(tetramethyldiphosphan)nickel(77659-49-5)

Safety Data

• Hazardous Substances Data: 77659-49-5(Hazardous Substances Data)

Upstream product

• 3676-91-3 tetramethyldiphosphane 
• 13463-39-3 tetracarbonyl nickel 

Relevant articles and documents

Metallcarbonyl-Brueckenligand-Sechsringsysteme

Directed syntheses yielded numerous six-membered ring complexes 5 and 9 of the type LnM - (EMe2 - E'Me2)2M'Ln with M, M' = Cr, Mo, W, Mn, Fe, Co, Ni and E, E' = P, As.Precursors were mononuclear organometallic Lewis bases LnM - EMe2 - E'Me2 and LnM(EMe2 - E'Me2)2 whose ligands EMe2 - E'Me2 were partly synthesized in the complex.Side reactions of the syntheses produced among others chain-like polynuclear complexes some of which were oligomeric.