77944-28-6

Basic information

• Product Name: {2-[((Z)-Hex-4-ene)-2-sulfonyl]-1,1-dimethyl-ethyl}-benzene
• CAS NO: 77944-28-6
• Molecular Weight: 280.431
• Mol File: 77944-28-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {2-[((Z)-Hex-4-ene)-2-sulfonyl]-1,1-dimethyl-ethyl}-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: {2-[((Z)-Hex-4-ene)-2-sulfonyl]-1,1-dimethyl-ethyl}-benzene(77944-28-6)
• EPA Substance Registry System: {2-[((Z)-Hex-4-ene)-2-sulfonyl]-1,1-dimethyl-ethyl}-benzene(77944-28-6)

Safety Data

• Hazardous Substances Data: 77944-28-6(Hazardous Substances Data)

Upstream product

• 67686-36-6 Sodium Neophylsulfinate 
• 592-46-1 hexa-2,4-diene 
• 5194-51-4 (2E)-2,6-hexadiene 

Relevant articles and documents

Regio- and Stereoselective Hydrosulfonylation of Conjugated Dienes via a (?-Allyl)palladium Complex

The combination of a sulfonylpalladation of acyclic dienes 1 (with 2 equiv of NaSO2R and 1 equiv of PdCl2 in acetic acid or acetic acid-H2O at 50-80 deg C under air) and a protiodepalladation of the thus obtained palladium complexes 3 with dimethylglyoxime (in a protic solvent at room temperature) provides di- and trisubstituted (Z)-Δ3-sulfones 12 selectively, irrespective of the stereochemistry of the starting dienes.Similar treatment of 1-vinylcycloalkenes 5 (n (1,3) strain between Pd and the substituent on the allylic position.