78339-63-6

Basic information

• Product Name: (2R,4aR,8aS)-2-p-Tolyloxy-hexahydro-benzo[1,3,2]dioxaphosphinine 2-oxide
• Synonyms: (2R,4aR,8aS)-2-p-Tolyloxy-hexahydro-benzo[1,3,2]dioxaphosphinine 2-oxide
• CAS NO: 78339-63-6
• Molecular Weight: 282.276
• Mol File: 78339-63-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4aR,8aS)-2-p-Tolyloxy-hexahydro-benzo[1,3,2]dioxaphosphinine 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4aR,8aS)-2-p-Tolyloxy-hexahydro-benzo[1,3,2]dioxaphosphinine 2-oxide(78339-63-6)
• EPA Substance Registry System: (2R,4aR,8aS)-2-p-Tolyloxy-hexahydro-benzo[1,3,2]dioxaphosphinine 2-oxide(78339-63-6)

Safety Data

• Hazardous Substances Data: 78339-63-6(Hazardous Substances Data)

Upstream product

• 4187-59-1 trans-2-hydroxymethylcyclohexanol 
• 106-44-5 p-cresol 
• 78339-65-8 2-fluoro-2-oxo-5,6-tetrametylene-1,3,2-dioxaphosphorinane 
• 74410-72-3 2-chloro-2-oxo-5,6-tetramethylene-1,3,2-dioxaphosphorinane 

Relevant articles and documents

Silicon Phosphorus Analogies. Fluoride Activation of Nucleophilic Displacement at the Tetrahedral Phosphorus: An Example of Nucleophilic Assistance to Nucleophilic Substitution. 3

We report a mechanistic study of the activation of alcoholysis of the P-X bond (X= Cl, F) by F(1-).Cis and trans isomers of 2-halogeno-5-(chloromethyl)-5-methyl-2-oxo-1,3,2-dioxaphosphorinanes, 1 and 2, or their 2-thio analogues, 3 and 4, and epimeric 2-h