78905-13-2

Basic information

• Product Name: Silane, trimethyl[1-(phenylthio)-2-propenyl]-
• CAS NO: 78905-13-2
• Molecular Formula: C12H18SSi
• Molecular Weight: 222.426
• Mol File: 78905-13-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[1-(phenylthio)-2-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[1-(phenylthio)-2-propenyl]-(78905-13-2)
• EPA Substance Registry System: Silane, trimethyl[1-(phenylthio)-2-propenyl]-(78905-13-2)

Safety Data

• Hazardous Substances Data: 78905-13-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 5296-64-0 allyl phenyl thioether 
• 123289-30-5 1-(Phenylthio)-1-(trimethylsilyl)-1,2-propadiene 
• 88410-20-2 (1-Benzenesulfinyl-propa-1,2-dienyl)-trimethyl-silane 
• 100-52-7 benzaldehyde 
• 123-72-8 butyraldehyde 
• 59376-64-6 (2E)-3-(trimethylsilyl)prop-2-en-1-ol 
• 882-33-7 diphenyldisulfane 
• 6212-77-7 1-phenylthio-1-propyne 
• 5272-36-6 3-trimethylsilyl-2-propyn-1-ol 
• 17891-78-0 1,3-bis(trimethylsilyl)propene 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 88904-66-9 (Z)-2-Cyclopentyl-5-phenylsulfanyl-5-trimethylsilanyl-pent-4-en-2-ol 
• 79409-67-9 (Z)-3-Phenethyl-1-phenyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol 
• 79409-62-4 (Z)-4-Phenylsulfanyl-1-p-tolyl-4-trimethylsilanyl-but-3-en-1-ol 
• 79409-61-3 (Z)-1-(2-Chloro-phenyl)-4-phenylsulfanyl-4-trimethylsilanyl-but-3-en-1-ol 
• 127901-04-6 (Z)-1-Phenyl-4-phenylsulfanyl-4-trimethylsilanyl-but-3-en-1-ol 
• 127901-15-9 (Z)-2,2-Dimethyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol 
• 107657-93-2 1-phenylthio-1-decene-4-one 
• 110362-94-2 1-phenylthio-2-decene-4-one 
• 84029-07-2 (1Z,5Z)-3-Methyl-1-phenyl-6-phenylsulfanyl-6-trimethylsilanyl-hexa-1,5-dien-3-ol 
• 84029-08-3 (Z)-4-Phenyl-7-phenylsulfanyl-7-trimethylsilanyl-hept-6-en-2-one 
• 88904-70-5 (E)-2-Cyclopentyl-6-methyl-5-phenylsulfanyl-hepta-3,5-dien-2-ol 
• 88904-73-8 [(1Z,3Z)-4-Cyclopentyl-1-(1-methoxy-1-methyl-ethyl)-penta-1,3-dienylsulfanyl]-benzene 
• 84051-52-5 (E)-(S)-2-((1aR,3aR,3bS,5aS,6S,8aS,8bS,10R)-10-Methoxy-3a,5a-dimethyl-hexadecahydro-cyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-6-methyl-5-phenylsulfanyl-hepta-3,5-dien-2-ol 
• 84051-56-9 (3Z,5E)-6-((3S,8S,9S,10R,13S,14S,17R)-3-Methoxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-2-methyl-3-phenylsulfanyl-hepta-3,5-dien-2-ol 

Relevant articles and documents

Stereoselective preparation of (E)- and (Z)-di- and trisubstituted 1,3-butadienes

Abstract The reaction of γ-(trimethylsilyl)allyltitanocenes, generated by the desulfurizative titanation of trimethylsilyl-substituted allylic sulfides with the titanocene(II)-1-butene complex, with ketones produced β-hydroxy silanes with good to complete

Synthesis of Vinylcyclopropanes from Epoxides

Ring-opening of epoxides 1 by heteroatom-substituted allyl anions 2 occurs with high regioselectivity.In situ tosylation of the resulting alkoxides 3 or tosylation of the corresponding alcohols 4 yields 4-pentenyl tosylates 5.Anion generation by deprotona

Acid-Catalyzed Regioselective Acylation of α-Silylallylic Sulfides and Its Application to a Novel Cyclopentannelation and Furan Annelation

Introduction of a silyl group at the α-position of allylic sulfides, followed by the aluminum chloride-catalyzed reaction of the resulting α-silylallylic sulfides with acid chlorides resulted in regioselective acylation at the γ-position of the allylic system to give γ-acylated vinylic sulfides, chemically equivalent to 1,4-dicarbonyl compounds.Heating of the products in refluxing benzene with an equimolar amount of p-toluenesulfonic acid produced 2-cyclopentanone derivatives.Treatment of the acylated products with an equimolar amount of concentrated sulfuric acid gave α-phenylthiofuran derivatives.These procedures provide a novel method for cyclopentannelation and furan annelation.Keywords - α-silylallylic sulfide; acid chloride; aluminum chloride; acid-catalyzed acylation; vinylic sulfide; 2-cyclopentanone; α-phenylthiofuran; furan; cyclopentannelation; furan annelation