79371-37-2Relevant articles and documents
METHOD FOR PRODUCING CARBAMATE AND METHOD FOR PRODUCING ISOCYANATE
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, (2021/06/22)
The present invention provides a method for producing a carbamate that includes a step (1) and a step (2) described below: (1) a step of producing a compound (A) having a urea linkage, using an organic primary amine having at least one primary amino group per molecule and at least one compound selected from among carbon dioxide and carbonic acid derivatives, at a temperature lower than the thermal dissociation temperature of the urea linkage; and(2) a step of reacting the compound (A) with a carbonate ester to produce a carbamate.
Isocyanates From Primary Amines and Carbon Dioxide: 'Dehydration' of Carbamate Anions
Waldman, Thomas E.,McGhee, William D.
, p. 957 - 958 (2007/10/02)
Carbamate anions, derived from primary amines CO2 and an added base (e.g.NEt3), undergo rapid reaction with electrophilic 'dehydrating agents' (e.g.POCl3, P4O10) to give the corresponding isocyanates in excellent yields.