79414-66-7

Basic information

• Product Name: 1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE
• Synonyms: 1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE;1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose;2,4-Di-O-benzyl-1,3,6-tri-O-acetyl-α-D-glucopyranose;2,4-Bis-O-(phenylMethyl)-α-D-glucopyranose Triacetate
• CAS NO: 79414-66-7
• Molecular Formula: C₂₆H₃₀O₉
• Molecular Weight: 486.51
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives
• Mol File: 79414-66-7.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE(79414-66-7)
• EPA Substance Registry System: 1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE(79414-66-7)

Safety Data

• Hazardous Substances Data: 79414-66-7(Hazardous Substances Data)

Usage

Uses

2,4-Di-O-benzyl-1,3,6-tri-O-acetyl-α-D-glucopyranose (cas# 79414-66-7) is a compound useful in organic synthesis.

Upstream product

• 86861-42-9 1,6-anhydro-2,4-di-O-benzyl-β-D-mannopyranose 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 108-24-7 acetic anhydride 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 35303-86-7 (2R,3S,4S,5R,6S)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-ol 
• 100-39-0 benzyl bromide 
• 86900-44-9 1,6-anhydro-4-O-benzyl-β-D-mannopyranose 
• 86861-43-0 3-O-Acetyl-1,6-anhydro-2,4-di-O-benzyl-β-D-mannopyranose 
• 61074-17-7 1,6-Anhydro-2,4-di-O-benzyl-β-D-galactopyranose 

Downstream Products

• 79705-30-9 3,6-di-O-acetyl-2,4-di-O-benzyl-α-D-galactopyranosyl bromide 
• 114283-82-8 Acetic acid (2R,3S,4S,5R)-2-acetoxymethyl-3,5-bis-benzyloxy-6-hydroxy-tetrahydro-pyran-4-yl ester 
• 79705-37-6 Benzyl-4-O-(3,6-di-O-acetyl-2,4-di-O-benzyl-α-D-galactopyranosyl)-2,3-O-isopropyliden-α-L-rhamnopyranosid 
• 79705-38-7 Benzyl-4-O-(3,6-di-O-acetyl-2,4-di-O-benzyl-β-D-galactopyranosyl)-2,3-O-isopropyliden-α-L-rhamnopyranosid 
• 143826-32-8 N-benzyloxycarbonyl-3-aminopropyl 2,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-3-O-levulinoyl-β-D-galactopyranoside 
• 143826-29-3 N-benzyloxycarbonyl-3-aminopropyl 3,6-di-O-acetyl-2,4-di-O-benzyl-β-D-galactopyranoside 
• 143826-33-9 N-benzyloxycarbonyl-3-aminopropyl 2,4-di-O-benzyl-3-O-levulinoyl-β-D-galactopyranoside 
• 143826-31-7 N-benzyloxycarbonyl-3-aminopropyl 2,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-β-D-galactopyranoside 
• 143826-30-6 N-benzyloxycarbonyl-3-aminopropyl 2,4-di-O-benzyl-β-D-galactopyranoside 

Relevant articles and documents

Corrected order in the simultaneous debenzylation-acetolysis of methyl 2,3,4,6-tetra-O-benzyl-α-d-glucopyranoside

The benzyl groups of methyl 2,3,4,6-tetra-O-benzyl-α-d-glucopyranoside were cleaved in the order of 6-O-Bn > 3-O-Bn > 4-O-Bn > 2-O-Bn under acid-mediated conditions in acetic anhydride. The order is a correction of that previously reported.

Synthesis of a pentasaccharide and a heptasaccharide corresponding to an ovarian glycoprotein; studies towards glycosylations

The syntheses of pentasaccharide I and heptasaccharide II, which correspond to an ovarian O-glycoprotein, are presented. The protected pentasaccharide 1 was prepared by condensing a trisaccharide donor (18c) with a disaccharide acceptor (8b), while conden

Building Units of Oligosaccharides, XLVII. - Synthesis of Tri- and Tetrasaccharide Sequences of N-Glycoproteins Including a β-D-Mannosidic Linkage

The trisaccharides α-D-Man-p-(1 -> 6)-β-D-Man-p-(1 -> 4)-D-GlcNAc (37) and α-D-Man-p-(1 -> 3)-β-D-Man-p-(1 -> 4)-D-GlcNAc (43) as well as the key tetrasaccharide α-D-Man-p-(1 -> 3)- 6)>-β-D-Man-p-(1 -> 4)-D-GlcNAc (51), which are parts of th