795305-25-8

Basic information

• Product Name: [Ni(2,2':6',6''-terpyridine)(2,4,6-trimethylphenyl)]Br
• CAS NO: 795305-25-8
• Molecular Weight: 491.053
• Mol File: 795305-25-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Ni(2,2':6',6''-terpyridine)(2,4,6-trimethylphenyl)]Br(CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(2,2':6',6''-terpyridine)(2,4,6-trimethylphenyl)]Br(795305-25-8)
• EPA Substance Registry System: [Ni(2,2':6',6''-terpyridine)(2,4,6-trimethylphenyl)]Br(795305-25-8)

Safety Data

• Hazardous Substances Data: 795305-25-8(Hazardous Substances Data)

Upstream product

• 1148-79-4 2,2':6,2''-terpyridine 

Downstream Products

• 1108202-02-3 [Ni(2,2':6',6''-terpyridine)(2,4,6-trimethylphenyl)]PF₆ 

Relevant articles and documents

Back-bonding in organonickel complexes with terpyridine ligands - A structural approach

A series of organonickel complexes [(R′terpy)Ni(aryl)]X (R′terpy = derivatives of 2,2′;6′,6″-terpyridine; R′ = 4-H, 4-Cl, 4-Tol and 4,4′,4″-tBu3; aryl = 2,6-dimethylphenyl = Xyl or 2,4,6-trimethylphenyl = Mes; X = Br or PF6) have been prepared and characterized. The crystal structures exhibit a number of intermolecular H bond type interactions, but the structure determining force seems to be the packing of the aryl co-ligands. The molecules reveal rather undistorted square planar coordination with a N3C ligand set, the central Ni-N bond being remarkably short, despite the expected strong trans influence of the aryl co-ligands. The longwavelength absorptions were assigned to charge transfer transitions. No emission is observed at ambient temperature in the solid and in solution and at low temperature in glasses.