79835-12-4

Basic information

• Product Name: N-(6-FORMYL-BENZO[1,3]DIOXOL-5-YL)-ACETAMIDE
• Synonyms: N-(6-FORMYL-BENZO[1,3]DIOXOL-5-YL)-ACETAMIDE
• CAS NO: 79835-12-4
• Molecular Formula: C₁₀H₉NO₄
• Molecular Weight: 207.18
• Mol File: 79835-12-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 431.3°C at 760 mmHg
• Flash Point: 214.6°C
• Appearance: /
• Density: 1.425g/cm³
• Vapor Pressure: 1.21E-07mmHg at 25°C
• Refractive Index: 1.656
• CAS DataBase Reference: N-(6-FORMYL-BENZO[1,3]DIOXOL-5-YL)-ACETAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(6-FORMYL-BENZO[1,3]DIOXOL-5-YL)-ACETAMIDE(79835-12-4)
• EPA Substance Registry System: N-(6-FORMYL-BENZO[1,3]DIOXOL-5-YL)-ACETAMIDE(79835-12-4)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Hazardous Substances Data: 79835-12-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H9NO4/c1-6(13)11-8-3-10-9(14-5-15-10)2-7(8)4-12/h2-4H,5H2,1H3,(H,11,13)

Upstream product

• 108-24-7 acetic anhydride 
• 23126-68-3 6-amino-benzo[1,3]dioxole-5-carbaldehyde 
• 712-97-0 6-nitro-1,3-benzodioxole-5-carbaldehyde 
• 57492-77-0 7-benzoylamino-6-methyl-[1,3]dioxolo[4,5-g]quinazolinium betaine 
• 109-73-9 N-butylamine 
• 6639-66-3 6-{(E)-[(4-methylphenyl)imino]methyl}-1,3-benzodioxol-5-amine 

Downstream Products

• 114284-73-0 Diethyl-(7-phenoxy-[1,3]dioxolo[4,5-g]quinolin-6-yl)-amine 
• 114284-70-7 Diethyl-(7-phenyl-[1,3]dioxolo[4,5-g]quinolin-6-yl)-amine 

Relevant articles and documents

COMPOUND

There is provided a compound having Formula (I), wherein each of R1, R2, R3, R4, R5, R6, R7, R8 and R9 are independently selected from (a) H, (b) R13, -OC(R13)3, -OCH(R13)2, -OCH2R13, -C(R13)3, -CH(R13)2, or -CH2R13 wherein R13 is a halogen; (c) -CN; (d) optionally substituted alkyl, (e) optionally substituted heteroalkyl; (f) optionally substituted aryl; (g) optionally substituted heteroaryl; (h) optionally substituted arylalkyl; (i) optionally substituted heteroarylalkyl; (j) hydroxy; (k) alkoxy; (I) aryloxy; (m) -SO2-alkyl; and (n) -N(R14)C(O)R15, wherein R14 and R15 are independently selected from H and hydrocarbyl, wherein the optional substituents of (d) (e) (T) (h) and (i) are selected from the group consisting of: C1-6 alkyl, halo, cyano, nitro, haloalkyl, hydroxy, C1-6 alkoxy, carboxy, carboxyalkyl, carboxamide, mercapto, amino, alkylamino, dialkylamino, sulfonyl, sulfonamido, aryl and heteroaryl; wherein n and p are independently selected from 0 and 1; X is an optional group selected from O, S, S=O, S(=O)2, C=O, S(=O)2NR16, C=ONR17, NR18, in which R16, R17, and R18 are independently selected from H and hydrocarbyl, R10 is selected from H and hydrocarbyl, R11 is selected from CR19R20 and C=O, in which R19 and R20 are independently selected from H and hydrocarbyl, R12 is selected from a substituted five or six membered carbon rings optionally containing one or more hetero atoms selected from N, S, and O and optionally having fused thereto a further ring, and wherein the one or more substituents are selected from hydrocarbyl groups.

ELECTRON DEFICIENT HETEROAROMATIC AMMONIOAMIDATES, XIX. N-(3-QUINAZOLINIO)AMIDATES, VII. THE PHOTOCHEMISTRY OF N-(3-QUINAZOLINIO)AMIDATES IN THE PRESENCE OF AMINES AND OF ACETAMIDE

Irradiation by Pyrex-filtered light of the quinazolinioamidates 1c-1f and of the dimers 2a and 2b in butylamine, of compound 2b in benzylamine and morpholine, and in the presence of acetamide in dioxane or dichloromethane, as well as of the adducts 5a and 5b in dichloromethane leads to complex mixtures of Type 6-16 products.While the compounds 6-9 are the products of Type II cleavage processes of the Type 3-5 adducts, the parent quinazolines 12 are formed from the amidates 1 themselves, amides 14 being the co-products in both cases.Compound 10a is formed by deacetylation of 9a during work-up, while compound 11b is a secondary photosubstitution product of 12b by the solvent dioxane.At least part of the compounds 13, 15 and 16 is the result of dark reactions.