803737-64-6

Basic information

• Product Name: [Ru(II)(C₆H₃(CH₂PPh₂)2-2,6)(2,2':6',2''-terpyridine)]Cl
• CAS NO: 803737-64-6
• Molecular Weight: 843.309
• Mol File: 803737-64-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(II)(C₆H₃(CH₂PPh₂)2-2,6)(2,2':6',2''-terpyridine)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(II)(C₆H₃(CH₂PPh₂)2-2,6)(2,2':6',2''-terpyridine)]Cl(803737-64-6)
• EPA Substance Registry System: [Ru(II)(C₆H₃(CH₂PPh₂)2-2,6)(2,2':6',2''-terpyridine)]Cl(803737-64-6)

Safety Data

• Hazardous Substances Data: 803737-64-6(Hazardous Substances Data)

Upstream product

• 1148-79-4 2,2':6,2''-terpyridine 
• 184714-11-2 (2,6-bis[(diphenylphosphino)methyl]phenyl)chloro(triphenylphosphine)ruthenium(II) 

Downstream Products

• 1003323-35-0 [Ru(II)(C₆H₂(CH₂PPh₂)2-2,6-Cl-4)(2,2':6',2''-terpyridine)](PF₆) 

Relevant articles and documents

Synthesis, crystal structure, and redox and photophysical properties of novel bisphosphinoaryl RuII-terpyridine complexes

Novel organometallic [Ru(PCP)(tpy)]Cl complexes, containing the terdentate coordinating monoanionic bisphosphinoaryl ligands [C6H 3(CH2PR2)2-2,6]- (PCP) (R = Ph (11); iPr (12)) and 2,2′:6′,2″-terpyridine, have been synthesized by two different synthetic pathways in good yields. The molecular structure in the solid state of [Ru{C2H2(CH 2PPh2)2-2,6}(tpy)](OTf) (14) has been determined by X-ray crystallography. The spectroscopic and electrochemical properties of the [Ru(PCP)(tpy)]Cl complexes were compared with those obtained for [Ru{C6H3(CH2NMe2) 2-2,6}(tpy)](Cl) (3) containing the monoanionic bisaminoaryl ligand [C6H3(CH2NMe2)2-2,6]- (NCN). The obtained results revealed that substitution of the NCN-pincer ligand by PCP-pincer ligands offers a powerful tool to tune the redox and photophysical properties as well as the reactivity of the ruthenium(II) metal centers in the resulting photoactive monomeric species.