80738-63-2

Basic information

• Product Name: dicyclohexylammonium salt of O,O-diethylphosphoroselenoic acid
• Synonyms: dicyclohexylammonium salt of O,O-diethylphosphoroselenoic acid
• CAS NO: 80738-63-2
• Molecular Weight: 398.385
• Mol File: 80738-63-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dicyclohexylammonium salt of O,O-diethylphosphoroselenoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: dicyclohexylammonium salt of O,O-diethylphosphoroselenoic acid(80738-63-2)
• EPA Substance Registry System: dicyclohexylammonium salt of O,O-diethylphosphoroselenoic acid(80738-63-2)

Safety Data

• Hazardous Substances Data: 80738-63-2(Hazardous Substances Data)

Upstream product

• 762-04-9 Diethyl phosphonate 

Downstream Products

• 34608-90-7 Dicyclohexyl-amine; compound with phosphoric acid diethyl ester 
• 80738-67-6 C₃₂H₅₂O₂₂P₂Se₂ 
• 2873-29-2 D-glucal triacetate 

Relevant articles and documents

O,O-DIALKYLPHOSPHOROSELENOIC ACIDS AS FUNCTIONALISING REAGENTS OF MONOSACCHARIDES-III A NOVEL SYNTHESIS OF UNSATURATED SUGARS BY DEOXYGENATION OF SUGAR EPOXIDES WITH DIALKYLPHOSPHOROSELENOIC ACIDS

Sugar epoxides are transformed in almost quantitative yields, under mild reaction conditions, into their corresponding unsaturated monosaccharides by reaction with O,O-dialkylphosphoroselenoic acids salts.A mechanism involving the formation of a penta-coordinate phosphorus intermediate is proposed. The deoxygenation was performed with the following sugar epoxides: 5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose (1), 5,6-anhydro-1,2-O-cyclohexylidene-α-D-glucofuranose (2), methyl-2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside (3), methyl-2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside (4) and 3,4,6-tri-O-acetyl-1,2-anhydro-α-D-glucopyranose (Brigl's anhydride) (5).