80922-14-1Relevant articles and documents
Double bond formation based on nitroaldol reaction and radical elimination: A prototype segment connection method for the total synthesis of nigricanoside A dimethyl ester
Tsunoda, Takayuki,Fujiwara, Kenshu,Okamoto, Satoshi,Kondo, Yoshihiko,Akiba, Uichi,Ishigaki, Yusuke,Katoono, Ryo,Suzuki, Takanori
, p. 1846 - 1850 (2018/04/11)
During the course of our studies toward the total synthesis of nigricanoside A dimethyl ester, a prototype method for the connection of the left- and right-half segments at the C9′–C10′ double bond was developed using a model system. The method was based
Direct aziridination of nitroalkenes affording N-alkyl-C-nitroaziridines and the subsequent Lewis acid mediated isomerization to β-nitroenamines
Hao, Feiyue,Asahara, Haruyasu,Nishiwaki, Nagatoshi
supporting information, p. 5442 - 5445 (2017/11/06)
A mild and highly diastereoselective one-pot synthesis of trans-N-alkyl-C-nitroaziridines was achieved by treatment of nitroalkenes with aliphatic amines and N-chlorosuccinimide. Treatment of the obtained aziridines with a Lewis acid resulted in a facile ring opening reaction, accompanied by rearrangement and isomerization into functionalized (Z)-β-nitroenamines.
Asymmetric Hydroazidation of Nitroalkenes Promoted by a Secondary Amine-Thiourea Catalyst
Bellavista, Tiziana,Meninno, Sara,Lattanzi, Alessandra,Della Sala, Giorgio
, p. 3365 - 3373 (2015/11/03)
Chiral β-nitro azides are obtained by asymmetric addition of azides to nitroalkenes, with an enantioselectivity of up to 82% ee. The reaction, promoted by an easily accessible secondary amine-thiourea catalyst, is performed with azidotrimethylsilane in th
