80935-75-7

Basic information

• Product Name: Butanenitrile, 3-(phenylamino)-
• CAS NO: 80935-75-7
• Molecular Formula: C10H12N2
• Molecular Weight: 160.219
• Mol File: 80935-75-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Butanenitrile, 3-(phenylamino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanenitrile, 3-(phenylamino)-(80935-75-7)
• EPA Substance Registry System: Butanenitrile, 3-(phenylamino)-(80935-75-7)

Safety Data

• Hazardous Substances Data: 80935-75-7(Hazardous Substances Data)

Upstream product

• 53778-71-5 3-chlorobutyronitrile 
• 62-53-3 aniline 
• 4786-20-3 crotononitrile 
• 109-75-1 but-3-enenitrile 
• 77942-49-5 3,6-dihydro-6-methyl-1-phenyl-2-(1H)pyrimidinone 
• 4786-20-3 but-2-enenitrile 

Downstream Products

• 26458-40-2 3-anilino-butyric acid ethyl ester; hydrochloride 

Relevant articles and documents

On the mechanism of Ni(II)-promoted Michael-type hydroamination of acrylonitrile and its substituted derivatives

Michael-type hydroamination of acrylonitrile and its substituted derivatives promoted by Ni(ii) complexes is believed to proceed via an outer-sphere nucleophilic attack on the cationic adduct of the nitrile-coordinated substrate. As a test for the validit

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

The monomeric Cu(I) complexes (IPr)Cu(Z) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, Z = NHPh, OEt, or OPh) react with YH (Y = PhNH, PhCH2NH, EtO, or PhO) to catalytically add Y-H bonds across the C=C bond of electron-deficient olefins to yield anti-Markovnikov organic products. Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. Preliminary studies implicate an intermediate in which the C-Y bond forms through a nucleophilic addition pathway. Copyright

Ring Opening Reaction of 3,6-Dihydro-2-(1H)pyrimidinones with Hydroxylamine Hydrochloride

1,4,6-Trisubstituted 3,6-dihydro-2-(1H)pyrimidinones (Ia-d) easily underwent the ring opening reaction with hydroxylamine hydrochloride to afford the oximes (IIa-d) in good yields.In the case of 3,6-dihydro-6-methyl-1-phenyl-2-(1H)pyrimidinone (Ie), 2-anilinobutyronitrile (III) was obtained in addition to the oxime (IIe).Dihydro-2-(1H)pyrimidinone (IV) and -thiones (V and VI) did not undergo the ring opening reaction.