81095-47-8

Basic information

• Product Name: (C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3
• Synonyms: (C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3
• CAS NO: 81095-47-8
• Molecular Weight: 546.497
• Mol File: 81095-47-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3(81095-47-8)
• EPA Substance Registry System: (C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3(81095-47-8)

Safety Data

• Hazardous Substances Data: 81095-47-8(Hazardous Substances Data)

Upstream product

• 81064-35-9 (C₆H₄(CH₃)2Si(CH₃)3)Fe(CO)3⁽¹⁺⁾*PF₆^(1-)=(C₆H₄(CH₃)2Si(CH₃)3)Fe(CO)3PF₆ 
• 7605-30-3 ethyl 2-phenylsulfonylacetate 
• 75850-40-7 ethyl (phenylsulfonyl)sodioacetate 

Relevant articles and documents

Silanes in organic synthesis. 15. Silicon-directed hydride abstraction from ( 2-(trimethylsilyl )-1,3-cyclohexadiene )iron tricarbonyl complexes and nucleophilic addition to the derived cations

Several (2-(trimethylsilyl)-1,3-cyclohexadiene)iron tricarbonyl complexes were prepared and treated with triphenylcarbenium cation. In all cases, hydride abstraction proved to be completely regiospecific to deliver only silyl-symmetric η5 catio