812639-15-9Relevant articles and documents
Palladium-catalyzed asymmetric alkylation of ketone enolates [7]
Trost, Barry M.,Schroeder, Gretchen M.
, p. 6759 - 6760 (1999)
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Phosphination of Phenol Derivatives and Applications to Divergent Synthesis of Phosphine Ligands
Li, Chenchen,Zhang, Kezhuo,Zhang, Minghao,Zhang, Wu,Zhao, Wanxiang
supporting information, p. 8766 - 8771 (2021/11/20)
We describe a general and efficient protocol for the synthesis of organophosphine compounds from phenols and phosphines (R2PH) via a metal-free C-O bond cleavage and C-P bond formation process. This approach exhibits broad substrate scope and excellent functional group tolerance. The synthetic utilities of this protocol were demonstrated by the synthesis of chiral ligands via the various transformations of cyano groups and their applications in asymmetric catalysis.
Enol Acetates: Versatile Substrates for the Enantioselective Intermolecular Tsuji Allylation
Liu, Ji,Mishra, Sourabh,Aponick, Aaron
supporting information, p. 16152 - 16158 (2018/12/13)
A highly versatile enantioselective intermolecular Tsuji allylation that generates alpha-quaternary stereocenters is reported. The methodology utilizes a prochiral enol acetate as a substrate, which is the last class of the original Tsuji substrates to be