812639-20-6

Basic information

• Product Name: C₁₂H₁₈O₂
• Synonyms: C₁₂H₁₈O₂
• CAS NO: 812639-20-6
• Molecular Weight: 194.274
• Mol File: 812639-20-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₈O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₈O₂(812639-20-6)
• EPA Substance Registry System: C₁₂H₁₈O₂(812639-20-6)

Safety Data

• Hazardous Substances Data: 812639-20-6(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 78-94-4 methyl vinyl ketone 
• 812639-07-9 (2S)-2-methyl-2-(2-propen-1-yl)cyclohexanone 
• 7770-41-4 1-methyl-2-oxocyclohexanecarboxylic acid 2-propenyl ester 
• 86950-89-2 allyl (2-methylcyclohex-1-en-1-yl)carbonate 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 

Relevant articles and documents

Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation

Pd-catalyzed enantioselective alkylation in conjunction with further synthetic elaboration enables the formal total syntheses of a number of "classic" natural product target molecules. This publication highlights recent methods for setting quaternary and tetrasubstituted tertiary carbon stereocenters to address the synthetic hurdles encountered over many decades across multiple compound classes spanning carbohydrate derivatives, terpenes, and alkaloids. These enantioselective methods will impact both academic and industrial settings, where the synthesis of stereogenic quaternary carbons is a continuing challenge.