813445-46-4Relevant articles and documents
1,3-Bis(4-methylphenyl)triazene, 1-(4-chlorophenyl)-3-(4-fluorophenyl)- triazene and 1-(4-fluorophenyl)-3-(4-methylphenyl)triazene
Karadayi, Nevzat,Cakmak, Suekriye,Odabasoglu, Mustafa,Bueyuekguengoer, Orhan
, p. o303-o305 (2005)
The title 4,4′-disubstituted diphenyl-1,3-triazines, C 14H15N3, (I), C12H 9ClFN3, (II), and C13H12FN 3, (III), each contain a triazene group (-N=N-NH-) having an extended conformation. The dihedral angles between the two benzene rings in (I), (II) and (III) are 4.3, 3.4 and 6.5°, respectively. The molecules are almost entirely planar, with maximum deviations from the mean planes of 0.1087 (2), -0.1072 (7) and 0.1401 (3) A, respectively. In each compound, the molecules are linked by N-H...N hydrogen bonds to form chains and pack similarly in the crystal structures.
Manganese complexes with triazenido ligands encapsulated in NaY zeolite as heterogeneous catalysts
Ku?niarska-Biernacka, Iwona,Fonseca, António M.,Neves, Isabel C.
, p. 591 - 597 (2013/03/13)
Two different methods were described for the preparation of manganese complexes with triazenido derivative ligands encapsulated in NaY zeolite. The catalytic behaviour of the heterogeneous catalysts was evaluated for styrene and cyclohexanol oxidation rea
Pd-catalyzed C-H activation/C-N bond formation: A new route to 1-aryl-1H-benzotriazoles
Kumar, Rapolu Kiran,Ali, Md Ashif,Punniyamurthy, Tharmalingam
supporting information; experimental part, p. 2102 - 2105 (2011/06/25)
A method for the C-H activation of aryl triazene compounds followed by intramolecular amination is described. It involves the use of a catalytic amount of Pd(OAc)2 that efficiently effects the cyclization to provide 1-aryl-1H-benzotriazoles at moderate temperature.