816-78-4Relevant articles and documents
A Catalytic Intermolecular Formal Ene Reaction between Ketone-Derived Silyl Enol Ethers and Alkynes
Holmbo, Stephen D.,Godfrey, Nicole A.,Hirner, Joshua J.,Pronin, Sergey V.
supporting information, p. 12316 - 12319 (2016/10/07)
A catalytic formal ene reaction between ketone-derived silyl enol ethers and terminal alkynes is described. This transformation is uniquely capable of bimolecular assembly of 2-siloxy-1,4-dienes and can be used to access β,?-unsaturated ketones containing quaternary carbons in the α-position.
Asymmetric Reduction of Carbon-Carbon Double Bonds of Conjugated Enones with Fermenting Bakers' yeast
Sakai, Takashi,Matsumoto, Syuji,Hidaka, Syukou,Imajo, Norihisa,Tsuboi, Sadao,Utaka, Masanori
, p. 3473 - 3475 (2007/10/02)
Bakers' yeast reduction of α-substituted or β,β-disubstituted α,β-unsaturated ketones gave saturated chiral ketones with excellent optical purity, while the β,β-disubstituted derivatives remains intact.
Catalytic Oxidation of Alk-1-enes to Aldehydes
Feringa, Ben L.
, p. 909 - 910 (2007/10/02)
Aldehydes are the major products of the catalytic oxidation of alk-1-enes with air using a catalyst that comprises (MeCN)2PdClNO2, CuCl2, and a tertiary alcohol.