82053-85-8

Basic information

• Product Name: N,N-Dimethylisolongifolamine
• Synonyms: N,N-Dimethylisolongifolamine
• CAS NO: 82053-85-8
• Molecular Weight: 249.44
• Mol File: 82053-85-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-Dimethylisolongifolamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Dimethylisolongifolamine(82053-85-8)
• EPA Substance Registry System: N,N-Dimethylisolongifolamine(82053-85-8)

Safety Data

• Hazardous Substances Data: 82053-85-8(Hazardous Substances Data)

Upstream product

• 82053-87-0 Trimethyl-((1S,3aR,4S,8aS,9S)-4,8,8-trimethyl-decahydro-1,4-methano-azulen-9-ylmethyl)-ammonium; iodide 

Downstream Products

• 475-20-7 longifolene 

Relevant articles and documents

Longifolene-Derived Amines: A Comparative Hofmann Elimination Study with Isolongifolic Acid and Homoisolongifolic Acid as Precursors

Isolongifolic acid (2) and homoisolongifolic acid (3) have been transformed into the C15- and C16-N,N-dimethylamino derivatives (8) and (9), respectively.A comparative Hofmann elimination study has revealed that, although both 8 and 9 possess a β-hydrogen available for elimination, the product-outcome is significantly different in the two cases; the major compound in the case of 8 arises from a reversal of the quaternary base to the parent dimethylamine (54percent) although a trivial amount (10percent) of the expected longifolene is also formed; on the other hand, 9 generates the theoretically anticipated vinylnorlongifolane (13) in 37 percent yield comparable with that of the dimethylamine (9) (33percent).Pb(IV)-Cu(II) reaction on the primary acid (3) fails to give longifolene by oxidative decarboxylation.