82251-58-9

Basic information

• Product Name: ternary complex of 2,3-dichloro-5,6-dicyano-p-benzoquinone, dibenzo-18-crown-6 and t-butylammonium perchlorate
• CAS NO: 82251-58-9
• Molecular Weight: 761.01
• Mol File: 82251-58-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ternary complex of 2,3-dichloro-5,6-dicyano-p-benzoquinone, dibenzo-18-crown-6 and t-butylammonium perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: ternary complex of 2,3-dichloro-5,6-dicyano-p-benzoquinone, dibenzo-18-crown-6 and t-butylammonium perchlorate(82251-58-9)
• EPA Substance Registry System: ternary complex of 2,3-dichloro-5,6-dicyano-p-benzoquinone, dibenzo-18-crown-6 and t-butylammonium perchlorate(82251-58-9)

Safety Data

• Hazardous Substances Data: 82251-58-9(Hazardous Substances Data)

Upstream product

• 14187-32-7 dibenzo-18-crown-6 
• 18720-49-5 tert-Butylammonium perchlorate 
• 84-58-2 2,3-dicyano-5,6-dichloro-p-benzoquinone 

Relevant articles and documents

Synthesis, X-Ray Crystal Structure, and Reactivity of Ternary Complexes of Crown Ethers, Organic ?-Acceptors, and Salts

Benzo-and dibenzo-18-crown-6 (1) and (2) from charge-transfer complexes with tetracyanoethylene (TCNE) in chloroform with association constants of 2.6 +/- 0.2 and 4.5 +/- 0.4 l mol-1.In the presence of 1 equiv. of t-butylammonium perchlorate (ButNH3ClO4) a solid ternary complex of (2), TCNE, and ButNH3ClO4 is formed.Single-crystal X-ray analysis of a similar ternary complex of (2), ButNH3ClO4 and 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) revealed the close proximity of the perchlorate anion and DDQ.Ternary complexes of TCNE, crown ethers (1)-(3), and salts with nucleophilic anions (Br-, and Cl-, and F-) react to give the TCNE-. radical anion as proven by e.s.r. spectroscopy.In the presence of water and/or oxygen 18-crown-6 (3), TCNE, and ButNH3Br react to yield the 18-crown-6xButNH3(NC)2C=C(CN)O complex.