82546-74-5

Basic information

• Product Name: Germane, chlorodimethyl(phenylmethyl)-
• CAS NO: 82546-74-5
• Molecular Formula: C9H13ClGe
• Molecular Weight: 229.245
• Mol File: 82546-74-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Germane, chlorodimethyl(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Germane, chlorodimethyl(phenylmethyl)-(82546-74-5)
• EPA Substance Registry System: Germane, chlorodimethyl(phenylmethyl)-(82546-74-5)

Safety Data

• Hazardous Substances Data: 82546-74-5(Hazardous Substances Data)

Upstream product

• 578-51-8 2-bromobenzylchloride 
• 1529-48-2 dichlorodimethylgermanium 
• 137482-82-7 1,2-dibenzyltetramethyldigermane 
• 137482-81-6 benzylpentamethyldigermane 
• 100-39-0 benzyl bromide 
• 22702-77-8 1,2-dichlorotetramethyldigermane 
• 100-44-7 benzyl chloride 

Downstream Products

• 153771-89-2 benzyl-methoxy-dimethylgermane 
• 137482-82-7 1,2-dibenzyltetramethyldigermane 

Relevant articles and documents

Palladium-Catalyzed Germylation of Organic Halides with a Digermane. Unexpected Formation of Germylene-Insertion Type Products

Organic halides (RX) underwent dehalogenative germylation and germylene insertion type reactions with ClMe2GeGeMe2Cl in the presence of Pd(PPh3)4 as catalyst to give RGeMe2Cl and RGeMe2X respectively.

An Investigation of the Di-Grignard Approach to Metallabenzocyclobutenes of Group 14

The reactions of 1,2-dihydro-1-magnesabenzocyclobutane (5) with dichlorodimethylsilane (12a), dichloromethylgermane (12b) and dichloromethylstannane (12C) are reported; 1,2-dihydro-1,1-dimethyl-1-silabenzocyclobutene (14a) and 1,2-dihydro-1,1-dimethyl-1-germabenzocyclobutene (14b) were formed in high yields, but the tin analogue was not obtained.Eight-membered ring species, the dimers 17 and 18, were isolated for all three metals.Other products gave useful indications of the probable course of these interesting and complex reactions.