82605-86-5Relevant articles and documents
Three novel Cd(II) dithiocarbamate complexes: synthesis, structural diversity and fluorescence properties
Singh, Ravi Pratap,Maurya, Vinay Kumar,Prasad, Lal Bahadur,Siddiqui, Kafeel Ahmad
, p. 2867 - 2876 (2020/07/03)
Three new homoleptic cadmium (II) dithiocarbamate complexes having molecular formula [Cd(KL)2], (KL1 = C15H13N1F1S2) (1); (L2 = C13H11N1F1S2) (2); (L3 = C11H14N1O1S2) (3), have been synthesized and characterized by elemental analysis, spectroscopy (IR, 1H and 13CNMR and UV–Vis). Single crystal X-ray studies confirm that the complex 1 crystallises in Orthorhombic with space group Pna21 and holding dimeric structure. In this complex Cd2+ having distorted octahedral geometry about the metal centre forms 1D coordination polymeric structures. The dimeric form of complex 2 and 3 crystallizes in triclinic crystal lattice with space group P-1.
Palladium-catalyzed aryl iodide carbonylation as a route to imidazoline synthesis: Design of a five-component coupling reaction
Bontemps, Sebastien,Quesnel, Jeffrey S.,Worrall, Kraig,Arndtsen, Bruce A.
supporting information; body text, p. 8948 - 8951 (2011/10/19)
Take five: A new method employing aryl halide carbonylation to directly access heterocycles has been described (see scheme). In a single palladium-catalyzed reaction the catalyst mediates two consecutive carbonylation steps, thereby converting five components (aryl iodide, two units imine, and two units CO) into an imidazoline ring.
Reaction of Thiiranes with Azomethine Compounds
Sokolov, V. V.,Ogloblin, K. A.,Potekhin, A. A.
, p. 470 - 475 (2007/10/02)
Thiiranes add to imines and oximes to give thiazolidines.The addition of asymmetrical thiiranes is regioselective.The reaction of derivatives of asymmetrical carbonyl compounds with methylthiirane leads to mixtures of cis and trans stereoisomers of thiazo
