82867-59-2

Basic information

• Product Name: phosphonium, tributylphenyl-, chloride (1:1)
• Synonyms: Tributyl(phenyl)phosphonium chloride
• CAS NO: 82867-59-2
• Molecular Formula: C₁₈H₃₂P*Cl
• Molecular Weight: 314.8734
• Mol File: 82867-59-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: phosphonium, tributylphenyl-, chloride (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: phosphonium, tributylphenyl-, chloride (1:1)(82867-59-2)
• EPA Substance Registry System: phosphonium, tributylphenyl-, chloride (1:1)(82867-59-2)

Safety Data

• Hazardous Substances Data: 82867-59-2(Hazardous Substances Data)

Upstream product

• 100-59-4 phenylmagnesium chloride 
• 814-29-9 Tributylphosphine oxide 

Relevant articles and documents

Exploring an Umpolung strategy for quaternization of phosphorus

We propose a new, potentially widely-applicable, Umpolung approach for the synthesis of quaternary phosphonium salts R3PR1 X (X = Cl, Br) from phosphine oxides R3PO. The new organic group R1 is introduced via nucleophilic attack on an intermediate halophosphonium salt using a Grignard reagent R1MgX and replaces the traditional phosphine quaternization approach. Consequently, the new method does not suffer from the limited availability of many parent phosphines and is much faster than standard quaternization.