82892-06-6

Basic information

• Product Name: 1-(4-Bromo-phenyl)-2-methyl-2-nitro-propan-1-one
• CAS NO: 82892-06-6
• Molecular Weight: 272.098
• Mol File: 82892-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(4-Bromo-phenyl)-2-methyl-2-nitro-propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-Bromo-phenyl)-2-methyl-2-nitro-propan-1-one(82892-06-6)
• EPA Substance Registry System: 1-(4-Bromo-phenyl)-2-methyl-2-nitro-propan-1-one(82892-06-6)

Safety Data

• Hazardous Substances Data: 82892-06-6(Hazardous Substances Data)

Upstream product

• 147225-22-7 2-lithio-2-nitropropane 
• 82892-00-0 N-(4-bromobenzoyl)imidazole 
• 586-75-4 4-chlorobenzoyl chloride 

Relevant articles and documents

α-Nitro Ketones and Esters from Acylimidazoles

The anion of 2-(2-nitroethyl)-1,3-dioxolane (4), prepared from the corresponding 2-bromo compound (3), undergoes condensation with acylimidazoles to give the 3-nitro-4-oxobutanal acetals (9), which can serve as valuable polyfunctional intermediates.Condensation with 1-(methoxyoxalyl)imidazole gives the tetrafunctionalized methyl 4-(1,3-dioxolan-2-yl)-3-nitro-2-oxobutanoate (13), which, however, decomposed on attempted deprotection of the ester function.The syntheses in excellent yields of simple α-nitro ketones and α-nitro esters from acylimidazoles and nitroethane and 2-nitropropane are also described.