82944-84-1

Basic information

• Product Name: (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic aMide
• Synonyms: (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic aMide;(E)-N-diphenylphosphoryl-1-phenylethanimine
• CAS NO: 82944-84-1
• Molecular Formula: C₂₀H₁₈NOP
• Molecular Weight: 319.336781
• Mol File: 82944-84-1.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic aMide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic aMide(82944-84-1)
• EPA Substance Registry System: (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic aMide(82944-84-1)

Safety Data

• Hazardous Substances Data: 82944-84-1(Hazardous Substances Data)

Upstream product

• 10341-75-0 (E)-1-phenylethanone oxime 
• 1079-66-9 chloro-diphenylphosphine 
• 5994-87-6 diphenylphosphinamide 
• 4316-37-4 1,1,-diethoxy-1-phenylethane 
• 613-91-2 acetophenone oxime 
• 1499-21-4 Diphenylphosphinic chloride 

Downstream Products

• 540485-22-1 (S)-N-(1-cyano-1-phenylethyl)-P,P-diphenylphosphinamide 
• 898288-14-7 (R)-N-(1-cyano-1-phenylethyl)-P,P-diphenylphosphinamide 
• 5994-87-6 diphenylphosphinamide 
• 133726-93-9 2,6?diphenyl?4?(thiophen?2?yl)pyridine 
• 1707-03-5 diphenyl-phosphinic acid 
• 29738-09-8 (R)-2-amino-2-phenylpropanoic acid 
• 4507-41-9 2-amino-2-phenyl propanoate de methyle 
• 565-07-1 2-amino-2-phenylpropanoic acid 
• 360566-30-9 (R)-2-Amino-2-phenyl-propionic acid methyl ester 
• 1283154-37-9 P,P-diphenyl-N-{1-[dimethyl(phenyl)silyl]-1-phenylethyl}phosphinic amide 
• 133726-94-0 (2E)-N-(Diphenylphosphinyl)-1,3-diphenyl-2-propenimine 
• 39183-99-8 2-phenyl-1-azaazulene 
• 2627-86-3 (S)-1-phenyl-ethylamine 

Relevant articles and documents

SUBSTITUTED PYRROLIDINE AMIDES III

The invention relates to compounds according to general formula (I), which act as modulators of the glucocorticoid receptor and can be used in the treatment and/or prophylaxis of disorders which are at least partially mediated by the glucocorticoid receptor.

Asymmetric Transfer Hydrogenation in Thermomorphic Microemulsions Based on Ionic Liquids

A thermomorphic ionic-liquid-based microemulsion system was successfully applied for the Ru-catalyzed asymmetric transfer hydrogenation of ketones. On the basis of the temperature-dependent multiphase behavior of the targeted microemulsion, simple product separation as well as catalyst recycling could be realized. The use of water-soluble ligands improved the immobilization of the catalyst in the microemulsion phase and significantly decreased the catalyst leaching into the organic layer upon extraction of the product. Eventually, the optimized microemulsion system could be applied to a wide range of aromatic ketones that were reduced with good isolated yields (up to 98%) and enantioselectivities (up to 97%), while aliphatic ketones were less successful.

Activation of the Si-B Linkage: Copper-Catalyzed addition of nucleophilic silicon to imines

Activation of the Si-B bond through copper-catalyzed transmetalation quickly developed into a practical method to generate Cu-Si reagents These silicon nucleophiles cleanly add to aldehyde-derived imine electrophiles to form R-silylated amines in protic media, and no carbon-tonitrogen Brook-type rearrangement of the intermediate anion is observed. Aside from electron-withdrawing groups at the imine nitrogen atom, for example, SO2Tol and P(O)Ph2, previously delicate nitrogen substituents such as phenyl or benzhydryl are tolerated. The same protocol also allows the unprecedented addition to representative ketone-derived imines.