82959-19-1Relevant articles and documents
NOVEL OXY-PERFLUOROALKYLATION
Umemoto, Teruo,Kuriu, Yuriko,Nakayama, Shin-ichi
, p. 4101 - 4102 (1982)
(Perfluoroalkyl)phenyliodonium sulfonates underwent novel oxy-perfluoroalkylation with alkenes under oxygen atmosphere in the presence of a base.
ELECTROCHEMICAL SYNTHESIS OF PERFLUOROALKYLACETONES
Vol'pin, I. M.,Kurykin, M. A.,Grinberg, V. A.,Vasil'ev, Yu. B.,German, L. S.
, p. 1395 - 1400 (2007/10/02)
The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids RFCF2COOH (I), where RF = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e). and C7F15 (f), with isoprenyl acetate (II) was studied.The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode.The yield of the perfluoroalkylacetones comprised 30-37percent.
A NEW METHOD FOR THE PREPARATION OF α-(PERFLUOROALKYL) CARBONYL AND γ-(PERFLUOROALKYL)-α,β-UNSATURATED CARBONYL COMPOUNDS
Umemoto, Teruo,Kuriu, Yuriko,Nakayama, Shin-ichi,Miyano, Osamu
, p. 1471 - 1474 (2007/10/02)
RfI(Ph)OSO2CF3 or RfI(Ph)OSO3H smoothly reacted with various trimethylsilyl enol ethers under mild conditions to give α(perfluoroalkyl) carbonyl and γ=)perfluoroalkyl)-α,β-unsaturated carbonyl compounds in high yields.
