830345-63-6

Basic information

• Product Name: Benzene, [(3Z)-5,5-dimethyl-3-hexenyl]-
• CAS NO: 830345-63-6
• Molecular Formula: C14H20
• Molecular Weight: 188.313
• Mol File: 830345-63-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(3Z)-5,5-dimethyl-3-hexenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(3Z)-5,5-dimethyl-3-hexenyl]-(830345-63-6)
• EPA Substance Registry System: Benzene, [(3Z)-5,5-dimethyl-3-hexenyl]-(830345-63-6)

Safety Data

• Hazardous Substances Data: 830345-63-6(Hazardous Substances Data)

Upstream product

• 99810-76-1 2-(tert-butyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 62692-41-5 (E)-(4-bromobut-3-en-1-yl) benzene 
• 637-59-2 1-Bromo-3-phenylpropane 

Relevant articles and documents

Stereodivergent Olefination of Enantioenriched Boronic Esters

A stereodivergent coupling reaction between vinyl halides and boronic esters is described. This coupling process proceeds without a transition-metal catalyst, instead proceeding by electrophilic selenation or iodination of a vinyl boronate complex followed by stereospecific syn or anti elimination. Chiral, nonracemic boronic esters could be coupled with complete enantiospecificity. The process enables the highly stereoselective synthesis of either the E or Z alkene from a single isomer of a vinyl coupling partner.