832142-14-0 Usage
General Description
2-(1-(Methylsulfonyloxy)cyclopropyl)acetic acid is a chemical compound with the molecular formula C6H10O5S. It is a cyclopropylacetic acid derivative that contains a sulfonate ester group. 2-(1-(Methylsulfonyloxy)cyclopropyl)acetic acid is used in organic synthesis and can react with various nucleophiles to form a wide range of derivatives. It is also a potential building block for pharmaceuticals and agrochemicals due to its unique chemical structure and reactivity. The methylsulfonyloxy group in the compound provides a leaving group for substitution reactions, making it a versatile intermediate in organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 832142-14-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,3,2,1,4 and 2 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 832142-14:
(8*8)+(7*3)+(6*2)+(5*1)+(4*4)+(3*2)+(2*1)+(1*4)=130
130 % 10 = 0
So 832142-14-0 is a valid CAS Registry Number.
832142-14-0Relevant articles and documents
Fulvene Synthesis by Rhodium(I)-Catalyzed [2+2+1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides
Yoshizaki, Soichi,Shibata, Yu,Tanaka, Ken
supporting information, p. 3590 - 3593 (2017/03/21)
It has been established that a RhI+/segphos complex catalyzes the [2+2+1] cycloaddition of 1,6-diynes with cyclopropylideneacetamides to give substituted fulvenes in good yields. The reductive complexation of the product fulvenes with RhCl3 in EtOH furnished the corresponding dinuclear cyclopentadienyl RhIII complexes bearing a pendant amide moiety. These RhIII complexes were highly active catalysts for oxidative annulation and cyclization through C(sp2)?H and C(sp3)?H functionalization.
